{"id":"W2770667359","doi":"10.1007/s11243-017-0191-3","title":"On the kinetics and mechanism of the conversion of Cr(CO)5(κ1-P-dppm) to Cr(CO)4(κ2-P,P′-dppm) (dppm = 1,2-diphenylphosphinomethane): an alternative hypothesis","year":2017,"lang":"en","type":"article","venue":"Transition Metal Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":false,"ca_institutions":"Toronto Metropolitan University","funders":"Ryerson University","keywords":"Organometallic chemistry; Order (exchange); Kinetics; Chemistry; Stereochemistry; Combinatorics; Physics; Crystallography; Mathematics; Crystal structure","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004032642,0.000384259,0.0005889113,0.00004460027,0.0003552547,0.0000793473,0.001076272,0.0001859494,0.008890264],"category_scores_gemma":[0.0002171067,0.0002715997,0.0003897195,0.0001260729,0.0005219634,0.00014356,0.000111244,0.0002800127,0.00001392282],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005593896,"about_ca_system_score_gemma":0.00003754304,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001016752,"about_ca_topic_score_gemma":0.00000454169,"domain_scores_codex":[0.9978916,0.00006164817,0.0005263289,0.0005550577,0.000669705,0.0002956439],"domain_scores_gemma":[0.9972722,0.0003168848,0.0005339597,0.001565393,0.0001303815,0.0001812148],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001313848,0.000279465,0.00002316999,0.0003034942,0.0002519981,0.000002507046,0.0007097007,0.00002428491,0.9967458,0.0005257973,0.00002701855,0.0009754143],"study_design_scores_gemma":[0.0005836855,0.00005717173,0.0004395018,0.0001112367,0.0003766287,0.000009733667,0.0007770936,0.0002104459,0.9949425,0.001755408,0.0004369964,0.0002996412],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9891707,0.00008760887,0.0004206827,0.0008438689,0.00005231875,0.0001757069,0.0004917242,0.00002854324,0.008728804],"genre_scores_gemma":[0.9983308,0.00005959453,0.0002133608,0.0001405875,0.0001162235,0.00002512667,0.00003348475,0.00004663912,0.001034209],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009160032,"threshold_uncertainty_score":0.9999736,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03062037663564479,"score_gpt":0.2453828830746667,"score_spread":0.2147625064390219,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}