{"id":"W2770774138","doi":"10.1021/acs.orglett.7b03288","title":"Synthesis of <i>N</i>-Oxyureas by Substitution and Cope-Type Hydroamination Reactions Using <i>O</i>-Isocyanate Precursors","year":2017,"lang":"en","type":"article","venue":"Organic Letters","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Government of Canada; University of Ottawa","keywords":"Hydroamination; Isocyanate; Chemistry; Reactivity (psychology); Carbamate; Organic chemistry; Combinatorial chemistry; Catalysis; Polyurethane","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001417151,0.0004425436,0.0001592752,0.000145676,0.00009286399,0.000159353,0.0003378763,0.0002672814,0.0009210158],"category_scores_gemma":[0.000225071,0.0001684907,0.0001684959,0.0001133524,0.0001641424,0.0002861919,0.0002598406,0.0003319523,0.0003113669],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000158581,"about_ca_system_score_gemma":0.0001609333,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002669654,"about_ca_topic_score_gemma":0.0007015677,"domain_scores_codex":[0.9999064,0.00001173559,0.00001058379,0.00002926658,0.00002405132,0.00001792005],"domain_scores_gemma":[0.9999022,0.00001422212,0.00003769571,0.00001396655,0.00001573036,0.00001618536],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005906458,0.00001829257,0.0001305475,0.0001578458,0.000008424897,0.0001856591,0.00007542179,0.0001780768,0.9916563,0.0008753371,0.0001135277,0.006541427],"study_design_scores_gemma":[0.000007397674,0.0001844138,0.0004144759,0.000009390232,0.000007935244,0.0001620791,0.00001515502,0.0003910353,0.9947225,0.00006053335,0.004018211,0.000007006836],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9594355,0.002336025,0.02443244,0.00008773461,0.0001086946,0.0001540472,0.0002696619,0.0002275086,0.01294844],"genre_scores_gemma":[0.9795821,0.001695099,0.01514025,0.00005320777,0.00002156046,0.00008520605,0.0002341689,0.00006150598,0.003126835],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009210158,"threshold_uncertainty_score":0.003081083,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01160971813676944,"score_gpt":0.232431243997637,"score_spread":0.2208215258608675,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}