{"id":"W2770978888","doi":"10.1021/acssuschemeng.7b03298","title":"Mechanochemical Metal-Free Transfer Hydrogenation of Carbonyls Using Polymethylhydrosiloxane as the Hydrogen Source","year":2017,"lang":"en","type":"article","venue":"ACS Sustainable Chemistry & Engineering","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Fonds de recherche du Québec – Nature et technologies; Canada Foundation for Innovation; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; McGill University","keywords":"Silane; Chemistry; Catalysis; Solvent; Organic chemistry; Chemical engineering; Polymer; Green chemistry; Biomass (ecology); Solubility; Reaction mechanism","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002950601,0.0005398666,0.0005369863,0.0000404858,0.0004765902,0.0001609967,0.001970672,0.0004814732,0.000664379],"category_scores_gemma":[0.000987396,0.0005163861,0.0002847447,0.0001686027,0.0002303888,0.000302004,0.0005921816,0.0005959675,0.000003714535],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003506091,"about_ca_system_score_gemma":0.0002371826,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002848247,"about_ca_topic_score_gemma":4.850684e-7,"domain_scores_codex":[0.9973335,0.000009372707,0.0005784026,0.0006030441,0.0005676543,0.0009079703],"domain_scores_gemma":[0.9968591,0.0001068398,0.0002322548,0.002359729,0.0001915174,0.0002505627],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002378561,0.00006361773,0.000107061,0.001098284,0.0001842089,0.00004798355,0.0002672119,0.001316286,0.996596,0.0001953718,0.00001496522,0.00008521985],"study_design_scores_gemma":[0.0008816416,0.000006723402,0.000004492207,0.00008426519,0.0002082604,0.0001254108,0.00069668,0.002794116,0.9925921,0.0001627511,0.001917749,0.0005257874],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942883,0.001092552,0.0002356111,0.0003368997,0.000044874,0.0001254734,0.00002291831,0.0001957368,0.003657697],"genre_scores_gemma":[0.9958808,0.0000443473,0.00009844759,0.0000277339,0.0003420495,0.00003194615,0.00003002419,0.0001374946,0.003407187],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004003882,"threshold_uncertainty_score":0.9997288,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007036190782759238,"score_gpt":0.2119994274262587,"score_spread":0.2049632366434994,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}