{"id":"W2773040972","doi":"10.1021/acs.jced.7b00805","title":"Phase Behavior for Poly(vinylacetate) + Carbon Dioxide + Cosolvent Ternary Systems","year":2017,"lang":"en","type":"article","venue":"Journal of Chemical & Engineering Data","topic":"Phase Equilibria and Thermodynamics","field":"Engineering","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Ministry of Science and Technology of the People's Republic of China; Ministry of Education of the People's Republic of China","keywords":"Cloud point; Ternary operation; Bubble point; Supercritical carbon dioxide; Thermodynamics; Chemistry; Ternary numeral system; Acetic acid; Polyvinyl acetate; Supercritical fluid; Phase (matter); Carbon dioxide; Phase transition; Ethyl acetate; Bubble; Organic chemistry; Aqueous solution; Polymer; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002445981,0.0002149191,0.0003997485,0.00007269669,0.00003082463,0.0001087768,0.001345966,0.0001055037,0.000002656895],"category_scores_gemma":[0.000152718,0.0002044455,0.0001131978,0.00002906427,0.00002683143,0.000453003,0.0001749813,0.0003003964,9.758136e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001064644,"about_ca_system_score_gemma":0.00002593044,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008114806,"about_ca_topic_score_gemma":1.896668e-7,"domain_scores_codex":[0.9988087,0.000004601472,0.0004981529,0.0001554254,0.000224566,0.0003085757],"domain_scores_gemma":[0.9985061,0.00005185162,0.0001907144,0.0009891242,0.0000507206,0.0002114656],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"simulation_or_modeling","study_design_scores_codex":[0.0000600249,0.0001533914,0.00006615166,0.0001879051,0.0001882408,0.0001176116,0.00001827578,0.002658719,0.9944958,0.00005053072,0.0003187674,0.001684585],"study_design_scores_gemma":[0.002809862,0.0001017395,0.00005944063,0.0002751126,0.0001955267,0.0003181414,0.00000473092,0.8823737,0.1095227,0.00001699866,0.003998577,0.000323518],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9782327,0.001603313,0.0173995,0.00003548059,0.001854899,0.0001875994,0.0005320256,0.00008853382,0.00006588497],"genre_scores_gemma":[0.9971983,0.00004805467,0.001712694,0.000003126117,0.0008414119,0.0000114947,0.000100889,0.00007178479,0.00001217595],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.8849731,"threshold_uncertainty_score":0.8337044,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03042707605500486,"score_gpt":0.2899383062913235,"score_spread":0.2595112302363187,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}