{"id":"W2774360463","doi":"10.1055/s-0036-1591858","title":"Fe(BF4)2-Catalyzed Inter- and Intramolecular Carbonyl-Ene Reaction of Trifluoropyruvate","year":2017,"lang":"en","type":"article","venue":"Synlett","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Chemistry; Citronellal; Ene reaction; Intramolecular force; Catalysis; Lewis acids and bases; Medicinal chemistry; Organic chemistry; Lewis acid catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003210923,0.0006798028,0.0003009358,0.0002205481,0.000197052,0.0001847983,0.000305748,0.0003281091,0.001176688],"category_scores_gemma":[0.0001483744,0.0001251727,0.0002356597,0.000164401,0.0002087891,0.0003573166,0.0003057142,0.0004786211,0.0004106679],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000229801,"about_ca_system_score_gemma":0.0001565963,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005720565,"about_ca_topic_score_gemma":0.001553407,"domain_scores_codex":[0.9998339,0.00002569848,0.000009470737,0.00003045856,0.00003218489,0.00006821825],"domain_scores_gemma":[0.9999318,0.00001189197,0.00001584855,0.000008858509,0.00001249749,0.00001901728],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001859895,0.00006668723,0.0002277857,0.0001392589,0.00002077557,0.0002187506,0.00007500186,0.0003146817,0.9887283,0.0005866325,0.0001360911,0.009300088],"study_design_scores_gemma":[0.000008662878,0.0001391718,0.0004339905,0.000003801054,0.00001018971,0.0001136326,0.00001169752,0.0003090049,0.9967277,0.00002495117,0.002210349,0.000006701991],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9582655,0.003485435,0.02418877,0.0001375969,0.0001010105,0.000102515,0.0003224309,0.0002752201,0.01312151],"genre_scores_gemma":[0.985301,0.001029036,0.008572529,0.00001905693,0.0000111913,0.00001992218,0.0002366496,0.00002799721,0.004782713],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001176688,"threshold_uncertainty_score":0.00393641,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01550262317702291,"score_gpt":0.2769314886110978,"score_spread":0.2614288654340749,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}