{"id":"W2774678905","doi":"10.1039/c7dt04350c","title":"Divergent reactivity of nucleophilic 1-bora-7a-azaindenide anions","year":2017,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"Calgary Laboratory Services; University of Calgary","funders":"Academy of Finland; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Emil Aaltosen Säätiö; Alexander von Humboldt-Stiftung","keywords":"Carboxylation; Chemistry; Nucleophile; Alkyl; Reactivity (psychology); Medicinal chemistry; SN2 reaction; Halide; Boron; Aromatization; Nucleophilic substitution; Ring (chemistry); Photochemistry; Inorganic chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006081067,0.0006247628,0.000670602,0.0002041478,0.0002929938,0.0005833927,0.0004983634,0.000666359,0.002567833],"category_scores_gemma":[0.0003994849,0.0002594737,0.000220809,0.0001464302,0.0004585565,0.0004069275,0.0003340298,0.0006357191,0.0007832302],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003665379,"about_ca_system_score_gemma":0.0002931128,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003828691,"about_ca_topic_score_gemma":0.0006902007,"domain_scores_codex":[0.9996408,0.00005560188,0.00001896445,0.0001130514,0.0000828555,0.00008876627],"domain_scores_gemma":[0.999772,0.00007189235,0.00006833077,0.00001957058,0.00003824869,0.00003003941],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001931257,0.000006690052,0.0001149016,0.00008574012,0.000006201559,0.0000646425,0.00003291176,0.0001013077,0.9980845,0.000264748,0.00004638311,0.0009988185],"study_design_scores_gemma":[0.0000249697,0.0001868767,0.0006363934,0.000005493847,0.000008669964,0.0001445394,0.00002792774,0.0004199658,0.9961579,0.0001136524,0.002260718,0.00001289766],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9908468,0.001651698,0.002321262,0.0001125115,0.00005979603,0.00003430197,0.0003694434,0.00009355202,0.004510689],"genre_scores_gemma":[0.9941479,0.0007590176,0.002864714,0.00005350973,0.00001556488,0.00004566923,0.0002764011,0.00003745916,0.001799771],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002567833,"threshold_uncertainty_score":0.008590221,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01844774891970258,"score_gpt":0.258774247934262,"score_spread":0.2403264990145594,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}