{"id":"W2777033171","doi":"10.1002/chem.201706081","title":"Wurster‐Type Nanographenes as Stable Diradical Dications","year":2017,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Diradical; Steric effects; Electron paramagnetic resonance; Ground state; Antiaromaticity; Chemistry; Photochemistry; Crystallography; Aromaticity; Singlet state; Molecule; Excited state; Stereochemistry; Nuclear magnetic resonance; Organic chemistry; Atomic physics; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["sts","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004867372,0.0002388269,0.0002382288,0.00002103518,0.001638416,0.001028351,0.001476177,0.00005575386,0.008198584],"category_scores_gemma":[0.0006589016,0.0002011395,0.0001950506,0.00003857675,0.0003163836,0.0002398396,0.00026518,0.0004599291,0.0002903055],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004458924,"about_ca_system_score_gemma":0.0001144202,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007283635,"about_ca_topic_score_gemma":3.40299e-7,"domain_scores_codex":[0.9984824,0.00005040595,0.0004473579,0.0002813076,0.0003537707,0.0003847277],"domain_scores_gemma":[0.9978387,0.00005949516,0.0004576252,0.001128802,0.0001259564,0.0003894478],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0001260457,0.0002753685,0.008001172,0.0002201777,0.0002686562,0.0004788737,0.00048133,0.000004794561,0.9282194,0.00002480417,0.02351911,0.03838024],"study_design_scores_gemma":[0.001791413,0.00007507807,0.006172901,0.0009558618,0.0001890681,0.003055144,0.000783378,0.0004067233,0.209589,0.0008062593,0.7751487,0.001026502],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6871524,0.0005386816,0.00001831042,0.0008186699,0.0001538666,0.0000153785,0.000005414552,0.00006059719,0.3112367],"genre_scores_gemma":[0.9828757,0.000252119,0.0005508268,0.00006873908,0.0009578243,0.000002203752,0.000009527262,0.00005818463,0.01522487],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.7516295,"threshold_uncertainty_score":0.9996613,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03104712126101306,"score_gpt":0.2510021365386763,"score_spread":0.2199550152776633,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}