{"id":"W2781311218","doi":"10.1021/acssuschemeng.7b02992","title":"Light-Induced Sonogashira C–C Coupling under Mild Conditions Using Supported Palladium Nanoparticles","year":2017,"lang":"en","type":"article","venue":"ACS Sustainable Chemistry & Engineering","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":61,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation","keywords":"Sonogashira coupling; Palladium; Catalysis; Aryl; Photochemistry; Chemistry; Irradiation; Absorption (acoustics); Excitation; Combinatorial chemistry; Materials science; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001786566,0.0004519612,0.0002256609,0.0001650654,0.0001367387,0.0002666042,0.000308845,0.0003445044,0.001130356],"category_scores_gemma":[0.0002411923,0.0002453692,0.0002044798,0.0001497471,0.0002775645,0.0003131581,0.0002499116,0.0006639539,0.0004630584],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003460589,"about_ca_system_score_gemma":0.0002624647,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001096745,"about_ca_topic_score_gemma":0.002776017,"domain_scores_codex":[0.9998263,0.00002461679,0.00001289748,0.00005169044,0.00004924652,0.00003533305],"domain_scores_gemma":[0.9999141,0.00002615578,0.00002023104,0.00001471418,0.00001436408,0.00001042988],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002677502,0.00001027021,0.00003910885,0.00006087933,0.000007663669,0.00005183305,0.00002017029,0.0000939762,0.9973016,0.0002451879,0.00008544912,0.002057184],"study_design_scores_gemma":[0.000003569763,0.00005174719,0.0001333625,0.000001532112,0.000004961218,0.00005173698,0.000005651157,0.0003809131,0.9982728,0.00002736083,0.001062452,0.000003906107],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9445376,0.002573656,0.04095822,0.0002315811,0.0001051627,0.0001044345,0.000232106,0.0004874761,0.01076964],"genre_scores_gemma":[0.9855177,0.0008648136,0.01063904,0.00004561193,0.00001279779,0.000031955,0.0001571573,0.00003643325,0.002694322],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001130356,"threshold_uncertainty_score":0.003781378,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02096993466599916,"score_gpt":0.2736246379946045,"score_spread":0.2526547033286053,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}