{"id":"W2781630804","doi":"10.1021/acs.jpcc.7b10246","title":"Structural Tuning of Boron Difluoride Formazanate Electrochemiluminescence Mediated by Tri-<i>n</i>-propylamine","year":2018,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; Ontario Ministry of Research, Innovation and Science; Canada Foundation for Innovation","keywords":"Electrochemiluminescence; Chemistry; Boron; Electrochemistry; Molecule; Photoluminescence; Photochemistry; Chemiluminescence; Difluoride; Propylamine; Materials science; Physical chemistry; Electrode; Inorganic chemistry; Organic chemistry; Amine gas treating; Optoelectronics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000245541,0.0001677891,0.0002672619,0.0000139324,0.00007806707,0.000007344775,0.0003624752,0.00008236842,0.000002787639],"category_scores_gemma":[0.000216555,0.0001032912,0.0001592693,0.0001593644,0.0003434212,0.000009197532,0.00007254488,0.0002304622,3.59969e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001837661,"about_ca_system_score_gemma":0.00004656769,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004195501,"about_ca_topic_score_gemma":8.521245e-7,"domain_scores_codex":[0.9990301,0.00004100763,0.0003425989,0.0001284248,0.0002463987,0.0002114545],"domain_scores_gemma":[0.9987601,0.00004427922,0.0004935535,0.0002490198,0.000380433,0.00007261603],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002674388,0.00003693034,0.00005941841,0.00001758244,0.00007453931,7.933001e-7,0.00003753815,0.000001365063,0.9980229,7.635131e-7,0.0009325764,0.0005481982],"study_design_scores_gemma":[0.0003150324,0.0004461003,0.00003935401,0.00002925565,0.00008692038,0.00004851118,0.00006511511,0.0003357081,0.9979054,0.0000579997,0.0005456602,0.0001249586],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9990163,0.0002301753,0.0003820948,0.0001096524,0.00001529859,0.00003613525,0.0000132958,0.000007903231,0.0001891731],"genre_scores_gemma":[0.9987893,0.00009606146,0.0002615457,0.00005002423,0.0006373334,4.635054e-7,0.00003275427,0.00001373565,0.0001187844],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006220348,"threshold_uncertainty_score":0.4212093,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004838779557802264,"score_gpt":0.2480049979165941,"score_spread":0.2431662183587918,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}