{"id":"W2782275502","doi":"10.1055/s-0036-1591868","title":"Mechanochemical Organic Synthesis: The Art of Making Chemistry Green","year":2018,"lang":"en","type":"article","venue":"Synlett","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":48,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Mechanosynthesis; Mechanochemistry; Chemistry; Organic synthesis; Nanotechnology; Biochemical engineering; Green chemistry; Organic chemistry; Catalysis; Reaction mechanism; Chemical engineering; Engineering; Ball mill","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00007193878,0.0001110479,0.0001191666,0.00001669813,0.00009088014,0.00001373489,0.0002890088,0.0001038626,0.007051414],"category_scores_gemma":[0.0001394072,0.0000875679,0.0001389453,0.0001265403,0.0001732751,0.00002779931,0.00008165049,0.0001769894,0.00005061359],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001918432,"about_ca_system_score_gemma":0.00002563891,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001064957,"about_ca_topic_score_gemma":0.00001202348,"domain_scores_codex":[0.9992955,0.00001032863,0.0001794369,0.0001824825,0.0001559145,0.0001763008],"domain_scores_gemma":[0.9992619,0.00009599141,0.00009126597,0.0004473157,0.00007075974,0.00003275374],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001623628,0.00003476615,0.00004112978,0.00005703058,0.00008108014,0.000004146943,0.00008760516,1.074654e-7,0.9963781,0.0000874835,0.002648165,0.0005641585],"study_design_scores_gemma":[0.00005953313,0.000004483124,0.000009452051,0.00009382196,0.00005813135,0.00005189271,0.0002162843,0.00002720358,0.9551305,0.0002795461,0.04397245,0.00009673496],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8166627,0.0001719094,0.001321972,0.001635114,0.0001390959,0.00007008046,0.00004927794,0.0001457116,0.1798042],"genre_scores_gemma":[0.9982107,0.000004091479,0.0001324834,0.000130136,0.0002605112,0.00001830396,0.000006648285,0.00001903226,0.001218133],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.181548,"threshold_uncertainty_score":0.9938563,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008332114122712043,"score_gpt":0.2335257752987127,"score_spread":0.2251936611760007,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}