{"id":"W2782548926","doi":"10.1021/acsomega.7b01529","title":"Novel Bonding Mode in Phosphine Haloboranes","year":2018,"lang":"en","type":"article","venue":"ACS Omega","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Prince Edward Island","funders":"Natural Sciences and Engineering Research Council of Canada; Atlantic Canada Opportunities Agency; Canada Foundation for Innovation","keywords":"Lewis acids and bases; Chemistry; Potential energy surface; Chemical physics; Computational chemistry; Potential energy; Maxima and minima; Dative case; Crystallography; Molecule; Physics; Mathematics; Organic chemistry; Atomic physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000318601,0.0000883807,0.00008881638,0.00007637573,0.00006073059,0.00002661991,0.0001225504,0.00006644915,0.0001167537],"category_scores_gemma":[0.00004266729,0.00009134821,0.00005274953,0.000197293,0.0000556403,0.00009588241,0.0000365839,0.000130128,0.0000196897],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002599079,"about_ca_system_score_gemma":0.0000131161,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003974487,"about_ca_topic_score_gemma":0.0004345495,"domain_scores_codex":[0.9994395,0.000002236021,0.0001279323,0.0001689613,0.00008550774,0.0001758619],"domain_scores_gemma":[0.9996482,0.00002561694,0.00003309291,0.000215856,0.00003767694,0.00003957067],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002348173,0.00009638691,0.001344162,0.00001450897,0.00001966026,0.0000120254,0.000268963,0.00001278822,0.9948685,0.0019322,0.0009139734,0.0004933062],"study_design_scores_gemma":[0.001015395,0.0000304208,0.0009472331,0.000116505,0.00002311572,0.00006353085,0.0003900107,0.0005211393,0.7920676,0.000997574,0.203501,0.0003264586],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9632037,0.00009614557,0.0004936997,0.0002363446,0.0001190612,0.00002390951,0.00002347707,0.0000579364,0.03574576],"genre_scores_gemma":[0.9973629,0.000008103753,0.0004356438,0.0001319732,0.0001357954,0.00001171908,0.00002445595,0.00001415515,0.001875331],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.202801,"threshold_uncertainty_score":0.3725072,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01389489579607169,"score_gpt":0.275510422178428,"score_spread":0.2616155263823563,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}