{"id":"W2782746280","doi":"10.1039/c7an01663h","title":"A quantitative approach for pesticide analysis in grape juice by direct interfacing of a matrix compatible SPME phase to dielectric barrier discharge ionization-mass spectrometry","year":2018,"lang":"en","type":"article","venue":"The Analyst","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":47,"is_retracted":false,"has_abstract":true,"ca_institutions":"Regional Municipality of Waterloo; University of Waterloo","funders":"","keywords":"Chemistry; Dielectric barrier discharge; Mass spectrometry; Ionization; Chromatography; Matrix (chemical analysis); Analytical Chemistry (journal); Interfacing; Pesticide; Ion source; Dielectric; Materials science; Ion; Optoelectronics; Organic chemistry; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007728597,0.0008138507,0.0003432998,0.0004206219,0.0002828778,0.0005760657,0.0005086273,0.0004753538,0.001058804],"category_scores_gemma":[0.0009636585,0.0003370188,0.0003238172,0.0002994838,0.0002861513,0.0003510513,0.0004132356,0.0006177986,0.0005267338],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003598848,"about_ca_system_score_gemma":0.0005218054,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009223929,"about_ca_topic_score_gemma":0.001687665,"domain_scores_codex":[0.9993649,0.0001038082,0.00002988813,0.0001761816,0.0002808514,0.00004435449],"domain_scores_gemma":[0.9996285,0.0001555542,0.00003402888,0.00003869585,0.000117077,0.00002610025],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002645281,0.000008236302,0.0001547425,0.00003374974,0.000005718056,0.00001456644,0.00001252067,0.00003653783,0.9975814,0.00002617714,0.00001251259,0.002087398],"study_design_scores_gemma":[0.000004136376,0.0002877556,0.001729073,0.000004391072,0.00001639518,0.0001660365,0.00002012377,0.001159641,0.9952719,0.00003506095,0.001298082,0.000007498485],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8062272,0.005387816,0.1816422,0.0003090381,0.0001267551,0.0006610894,0.001290576,0.0008197715,0.003535632],"genre_scores_gemma":[0.7191201,0.003118672,0.2736244,0.000177032,0.00003832732,0.0003691702,0.0006348885,0.0001081742,0.002809247],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001058804,"threshold_uncertainty_score":0.004087329,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01630148496129587,"score_gpt":0.3247520753284319,"score_spread":0.3084505903671361,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}