{"id":"W2782872430","doi":"10.1021/acsaem.7b00138","title":"2,3,5,6-Tetra(1<i>H</i>-tetrazol-5-yl)pyrazine: A Thermally Stable Nitrogen-Rich Energetic Material","year":2018,"lang":"en","type":"article","venue":"ACS Applied Energy Materials","topic":"Energetic Materials and Combustion","field":"Engineering","cited_by":62,"is_retracted":false,"has_abstract":true,"ca_institutions":"Defence Research and Development Canada; University of Ottawa","funders":"Defence Research and Development Canada","keywords":"Detonation; Detonation velocity; Pyrazine; Nitrogen; Raman spectroscopy; Thermal stability; Tetra; Energetic material; Thermal decomposition; Molecule; Materials science; Decomposition; Planarity testing; Chemistry; Mass spectrometry; Diffraction; Analytical Chemistry (journal); Crystallography; Organic chemistry; Explosive material; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001864891,0.0003644361,0.0002213427,0.0002228893,0.0002037922,0.0002080249,0.0004716217,0.0004441616,0.001231208],"category_scores_gemma":[0.0001050049,0.000212589,0.0001306837,0.0001563569,0.0002371918,0.0002806505,0.0002494139,0.0003262463,0.0005625697],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002882457,"about_ca_system_score_gemma":0.0001730362,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001049322,"about_ca_topic_score_gemma":0.0002669565,"domain_scores_codex":[0.9999012,0.00001812023,0.000007563799,0.00002153058,0.00002888288,0.0000228277],"domain_scores_gemma":[0.9999468,0.000006537114,0.00002223805,0.000006221657,0.000006658397,0.00001141871],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000355554,0.00001182418,0.00003244956,0.00006007666,0.000001866519,0.00007065952,0.0000103533,0.0001670677,0.9978352,0.0003609367,0.00006055258,0.001353362],"study_design_scores_gemma":[0.00001214265,0.0001967917,0.0003529605,0.000003606648,0.000005324037,0.0003219042,0.000007733856,0.0007526183,0.9948335,0.00004605775,0.003460976,0.000006461534],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.921072,0.002202996,0.06426715,0.0002491765,0.0001042935,0.000232081,0.0007378251,0.0006174773,0.01051698],"genre_scores_gemma":[0.9585836,0.000869528,0.03542866,0.0000579998,0.00001685864,0.0001324684,0.000347113,0.00005485522,0.00450896],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001231208,"threshold_uncertainty_score":0.004118741,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005600899594502038,"score_gpt":0.1818955426119997,"score_spread":0.1762946430174976,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}