{"id":"W2783526603","doi":"","title":"A new method for generating the cyclopropylmethyl radical, and generation of ketenes with Proton Sponge","year":2001,"lang":"en","type":"dissertation","venue":"TSpace","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Sponge; Proton; Chemistry; Geology; Physics; Paleontology; Nuclear physics","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002078837,0.0002895056,0.0003789818,0.00004461081,0.0001677263,0.00005968081,0.0001807248,0.0003676827,0.0002633727],"category_scores_gemma":[0.000450026,0.0001940708,0.0001024505,0.0001540863,0.00005834909,0.00005012203,0.00001421325,0.0003890805,9.154658e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005794484,"about_ca_system_score_gemma":0.0002537206,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005395116,"about_ca_topic_score_gemma":0.0002217587,"domain_scores_codex":[0.9986567,0.00003503801,0.0003260328,0.0004305185,0.0003180442,0.0002336858],"domain_scores_gemma":[0.9986424,0.0003657462,0.000368879,0.0003547045,0.0001308753,0.0001373464],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002455636,0.00003495279,0.00001431688,0.000524518,0.000103125,0.000001655257,0.0009739673,0.00003701672,0.9734971,0.0001261389,0.001508494,0.02293316],"study_design_scores_gemma":[0.000612054,0.00006998209,0.000009818774,0.0002060981,0.0002412465,0.00002149996,0.0009068769,0.006246239,0.965304,0.0003035399,0.02580334,0.0002752941],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.9330733,0.001798322,0.04243607,0.0009648326,0.0001614023,0.003155151,0.00003371732,0.0001407939,0.01823638],"genre_scores_gemma":[0.02912046,0.0009095593,0.7181987,0.000244075,0.00445164,0.006227602,0.003224185,0.0005042209,0.2371195],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.9039528,"threshold_uncertainty_score":0.7913978,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03160189333754274,"score_gpt":0.3661896267489805,"score_spread":0.3345877334114377,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}