{"id":"W2783589645","doi":"10.1002/anie.201710074","title":"Selective Production of Renewable <i>para</i>‐Xylene by Tungsten Carbide Catalyzed Atom‐Economic Cascade Reactions","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Catalysis for Biomass Conversion","field":"Engineering","cited_by":46,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Natural Science Foundation of China; Université Laval","keywords":"Hydrodeoxygenation; Catalysis; Intramolecular force; Chemistry; Cyclohexene; Atom economy; Deoxygenation; Photochemistry; Dehydrogenation; Organic chemistry; Selectivity","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001214991,0.0001572053,0.0001675427,0.000178864,0.0000632946,0.00002127067,0.0001636115,0.0001157577,0.0001885047],"category_scores_gemma":[0.00004124306,0.0001818906,0.00009727621,0.0001748421,0.00009279018,0.0005038797,0.00003269879,0.0001020744,0.00009319683],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006241545,"about_ca_system_score_gemma":0.00003261604,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001077698,"about_ca_topic_score_gemma":0.0002904409,"domain_scores_codex":[0.9989974,0.0000086838,0.0003262919,0.0002775685,0.000223835,0.0001661428],"domain_scores_gemma":[0.9993431,0.00002940933,0.000136694,0.0002107262,0.0002215321,0.00005855308],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003322101,0.00002497843,0.00008789574,0.00002136685,0.000153956,5.15006e-7,0.0001268288,0.0002755148,0.8703892,0.00001406774,0.1287578,0.0001146694],"study_design_scores_gemma":[0.0002943339,0.00002198329,0.0002057395,0.00004030768,0.00004420794,0.00002060565,0.00005632053,0.0008310157,0.9482292,0.00009791265,0.04999596,0.0001624325],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9748402,0.0001907176,0.002833686,0.0005732625,0.006236946,0.0002720368,0.0004304095,0.0003355249,0.01428727],"genre_scores_gemma":[0.995166,0.0001259164,0.00020347,0.00002036153,0.001552686,0.00004325463,0.001821635,0.00003180056,0.001034856],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07876188,"threshold_uncertainty_score":0.7417285,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008137420734376727,"score_gpt":0.2248394321676804,"score_spread":0.2167020114333037,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}