{"id":"W2783686985","doi":"10.1021/acs.inorgchem.7b02778","title":"Trifluoromethyl-Substituted Iridium(III) Complexes: From Photophysics to Photooxidation of a Biological Target","year":2018,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Lanthanide and Transition Metal Complexes","field":"Materials Science","cited_by":38,"is_retracted":false,"has_abstract":true,"ca_institutions":"Bombardier (Canada); Université de Montréal","funders":"Université Catholique de Louvain; Natural Sciences and Engineering Research Council of Canada; Fonds pour la Formation à la Recherche dans l’Industrie et dans l’Agriculture; Fonds De La Recherche Scientifique - FNRS","keywords":"Chemistry; Iridium; Trifluoromethyl; Photochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001471206,0.0001787203,0.0003368304,0.00002292349,0.00009415277,0.00003784857,0.0003730953,0.0001117557,0.009417025],"category_scores_gemma":[0.0000698896,0.000153359,0.00007484081,0.0003277709,0.0002208472,0.0001079556,0.00008706048,0.00008690393,0.0004177169],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003658679,"about_ca_system_score_gemma":0.00006754239,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002889915,"about_ca_topic_score_gemma":0.000007844793,"domain_scores_codex":[0.9987121,0.00003905819,0.0003746123,0.0003974228,0.0002423969,0.0002344688],"domain_scores_gemma":[0.999111,0.000084418,0.0001357858,0.0003779149,0.0001713794,0.0001194951],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001006269,0.00009267066,0.00007351598,0.00001851461,0.00001457814,0.000003151272,0.0002463955,0.000001267974,0.9990929,0.00003463783,0.0002722305,0.00004955367],"study_design_scores_gemma":[0.0005085389,0.00005323862,0.0007368381,0.00002713005,0.00001785147,0.000004671344,0.00008284472,0.00002529346,0.9961362,0.001513291,0.000701941,0.0001921287],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9936261,0.00004215762,0.004703838,0.00005031624,0.000186185,0.0001480655,0.0003726996,0.000108069,0.0007625735],"genre_scores_gemma":[0.9929236,0.000004310045,0.006314402,0.0001636286,0.0003432136,0.00001172649,0.0001852181,0.00001349788,0.00004043434],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008999309,"threshold_uncertainty_score":0.9914885,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02560830976634301,"score_gpt":0.2533149119185825,"score_spread":0.2277066021522395,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}