{"id":"W2784297608","doi":"10.1039/c7ob03005c","title":"Highly chemoselective intermolecular cross-benzoin reactions using an <i>ad hoc</i> designed novel N-heterocyclic carbene catalyst","year":2018,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"Trinity College","funders":"Irish Research Council","keywords":"Chemistry; Carbene; Benzoin; Intermolecular force; Catalysis; Umpolung; Acetonitrile; Combinatorial chemistry; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001618428,0.000297432,0.0001462287,0.0001037102,0.0001554333,0.0002420401,0.0003370024,0.0002133102,0.0008019021],"category_scores_gemma":[0.0001128528,0.000116329,0.0001230461,0.00009105611,0.0001976177,0.0002924596,0.0002388859,0.0004137324,0.000356216],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003757566,"about_ca_system_score_gemma":0.0002739666,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007839201,"about_ca_topic_score_gemma":0.002337251,"domain_scores_codex":[0.9998701,0.00001457762,0.00000935177,0.00003754385,0.00003567795,0.00003284366],"domain_scores_gemma":[0.9999611,0.000004991728,0.00001149429,0.000005306532,0.000008541833,0.000008528988],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006015826,0.00004818603,0.0001674919,0.00006085536,0.000008599724,0.00009722954,0.0000217018,0.0004242531,0.9918393,0.001834902,0.0002641113,0.005173094],"study_design_scores_gemma":[0.000008750668,0.0001012882,0.0002984526,0.000001726174,0.000005956435,0.0001297788,0.00000402125,0.0008300812,0.9951376,0.00006082004,0.003415664,0.000005864089],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9138781,0.001911569,0.05073528,0.0002349023,0.0001489253,0.0001405625,0.0003652165,0.0004634421,0.03212195],"genre_scores_gemma":[0.98616,0.0005558776,0.009823681,0.0000412972,0.00001328694,0.00002318599,0.0001738408,0.00003334276,0.003175557],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008019021,"threshold_uncertainty_score":0.002726376,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0142234087482995,"score_gpt":0.2714979926459241,"score_spread":0.2572745838976246,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}