{"id":"W2784321155","doi":"10.1021/acsomega.7b01744","title":"Cyclodextrin-Based Pseudorotaxanes: Easily Conjugatable Scaffolds for Synthesizing Hyperpolarized Xenon-129 Magnetic Resonance Imaging Agents","year":2018,"lang":"en","type":"article","venue":"ACS Omega","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"Lakehead University; Thunder Bay Regional Research Institute","funders":"Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research; BrightFocus Foundation","keywords":"Xenon; Chemistry; Nuclear magnetic resonance spectroscopy; Nuclear magnetic resonance; Nanotechnology; Materials science; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001675253,0.0002889061,0.0003003519,0.00007047191,0.0004473836,0.00008063321,0.0005274842,0.0001246363,0.0001589968],"category_scores_gemma":[0.0001300603,0.0003046866,0.000117033,0.0002406755,0.0002142407,0.0001809365,0.0000887208,0.0001128079,0.000068341],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001122433,"about_ca_system_score_gemma":0.00007124001,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008043138,"about_ca_topic_score_gemma":0.00000798909,"domain_scores_codex":[0.9982051,0.00001404068,0.000375176,0.0005920306,0.0002214792,0.0005921212],"domain_scores_gemma":[0.9983718,0.000272591,0.0001750424,0.0008546221,0.000191336,0.0001346559],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002765988,0.0003211455,0.008213443,0.000268817,0.00002039509,0.0000141166,0.0001092342,0.00001919425,0.8891352,0.003793992,0.005423906,0.09240399],"study_design_scores_gemma":[0.001700812,0.00006625005,0.0005317864,0.0002888559,0.0000705598,0.00001937397,0.00008989873,0.009673755,0.5065408,0.003420387,0.4769554,0.0006420945],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9170681,0.006170399,0.03812826,0.001260225,0.0001321181,0.00160682,0.000586565,0.001746973,0.03330057],"genre_scores_gemma":[0.9535745,0.00005146774,0.04223654,0.0005772173,0.0003113111,0.0006753575,0.0000483549,0.00009053876,0.002434698],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4715315,"threshold_uncertainty_score":0.9999405,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01812904452163281,"score_gpt":0.2818479236598687,"score_spread":0.2637188791382359,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}