{"id":"W2784565110","doi":"10.1021/acs.biomac.7b01642","title":"Chemo-enzymatic Synthesis of Clickable Xylo-oligosaccharide Monomers from Hardwood 4-<i>O</i>-Methylglucuronoxylan","year":2018,"lang":"en","type":"article","venue":"Biomacromolecules","topic":"biodegradable polymer synthesis and properties","field":"Materials Science","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"H2020 European Research Council; Natural Sciences and Engineering Research Council of Canada; Government of Ontario","keywords":"Chemistry; Oligosaccharide; Monomer; Polymerization; Propanoic acid; Polymer chemistry; Click chemistry; Organic chemistry; Aqueous solution; Bifunctional; Carbodiimide; Reagent; Combinatorial chemistry; Catalysis; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009098927,0.0005413693,0.0001982912,0.0001526638,0.00007681716,0.0001708988,0.0001888126,0.0002059082,0.0006319068],"category_scores_gemma":[0.00008603559,0.000171538,0.0002464788,0.0001721444,0.0001114101,0.0002066011,0.0001941721,0.0004167,0.0003926576],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001839024,"about_ca_system_score_gemma":0.0002047203,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004177233,"about_ca_topic_score_gemma":0.0009803249,"domain_scores_codex":[0.9999235,0.000006709349,0.000006895168,0.00001895331,0.00001904718,0.00002484149],"domain_scores_gemma":[0.9999363,0.000007574359,0.00002440192,0.00000708978,0.000007864888,0.00001670586],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000007002755,0.00000539461,0.00002190605,0.00001277358,0.000001129688,0.00001723765,0.000003384487,0.00003037881,0.999256,0.00003558545,0.000005799628,0.0006035037],"study_design_scores_gemma":[0.000001667747,0.00003894106,0.0003034155,6.9279e-7,0.000002566823,0.00002964619,0.000002336439,0.0001208859,0.9991442,0.000006005529,0.0003482926,0.000001287024],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9711238,0.0008333088,0.02449671,0.00006133743,0.0000362021,0.00009654463,0.0004118401,0.0002052472,0.002735007],"genre_scores_gemma":[0.9749051,0.0008331725,0.01955233,0.00004001811,0.000007503348,0.00006452153,0.0005078918,0.00005057171,0.004038753],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006319068,"threshold_uncertainty_score":0.002113938,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01670896711595296,"score_gpt":0.2278248063600171,"score_spread":0.2111158392440642,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}