{"id":"W2785059414","doi":"10.1021/acs.inorgchem.7b02803","title":"Diastereomerically Differentiated Excited State Behavior in Ruthenium(II) Hexafluoroacetylacetonate Complexes of Diphenyl Thioindigo Diimine","year":2018,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia; University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; U.S. Department of Energy","keywords":"Chemistry; Ultrafast laser spectroscopy; Ruthenium; Diimine; Photochemistry; Excited state; Denticity; Diastereomer; Ligand (biochemistry); Absorption spectroscopy; Photoluminescence; Nuclear magnetic resonance spectroscopy; Spectroscopy; Crystallography; Stereochemistry; Crystal structure; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001023108,0.0005300073,0.0007294962,0.00004711421,0.0001870901,0.00002941185,0.0006524561,0.0002510233,0.004718676],"category_scores_gemma":[0.00007119749,0.0005377817,0.0001742535,0.0003961344,0.0005343117,0.00009660575,0.0002906029,0.0005316521,0.00001678944],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000151294,"about_ca_system_score_gemma":0.00009587571,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001043809,"about_ca_topic_score_gemma":0.00005108931,"domain_scores_codex":[0.9972814,0.00001686162,0.0008561538,0.0006762478,0.0004058571,0.0007634268],"domain_scores_gemma":[0.9986057,0.00008686118,0.0002416943,0.0007008977,0.0001804705,0.0001844176],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002789214,0.0005970899,0.01269752,0.0003781446,0.0001464285,0.00001976109,0.001043965,6.375236e-7,0.9842232,0.000003486757,0.00006043223,0.0005503908],"study_design_scores_gemma":[0.001744787,0.0000792668,0.009901589,0.000138725,0.00009010628,0.0000338975,0.0002096035,0.00003438992,0.9868362,0.0001107042,0.0002914894,0.0005292255],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9918125,0.000342294,0.00003408254,0.00007498019,0.00004417089,0.0001361166,0.0002081101,0.0001708202,0.007176931],"genre_scores_gemma":[0.9973,0.0000980223,0.00004674451,0.00003008687,0.0001247639,0.00007112207,0.0001484075,0.00007052442,0.002110322],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005487512,"threshold_uncertainty_score":0.9997074,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01124818985932527,"score_gpt":0.231695687723949,"score_spread":0.2204474978646238,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}