{"id":"W2786099644","doi":"10.1021/jacs.8b00998","title":"The Catalytic Reaction of Nitroxides with Peroxyl Radicals and Its Relevance to Their Cytoprotective Properties","year":2018,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Electron Spin Resonance Studies","field":"Biochemistry, Genetics and Molecular Biology","cited_by":90,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation","keywords":"Chemistry; Nitroxide mediated radical polymerization; Radical; Photochemistry; Lipid peroxidation; Catalysis; Butylated hydroxytoluene; Aqueous solution; Antioxidant; Organic chemistry; Polymerization; Radical polymerization","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002003505,0.00009490124,0.0001818864,0.000004542301,0.0001345376,0.000008935638,0.0002212676,0.00002793769,1.691461e-7],"category_scores_gemma":[0.0003089313,0.00004159295,0.0001124369,0.0001187167,0.0008940309,0.000004721277,0.0001149713,0.0001603153,2.247809e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003991027,"about_ca_system_score_gemma":0.00006805846,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001395067,"about_ca_topic_score_gemma":0.000005374799,"domain_scores_codex":[0.9993657,0.00003541576,0.0001701507,0.0001162754,0.0001569662,0.000155421],"domain_scores_gemma":[0.9991487,0.00003593612,0.000348413,0.0001514528,0.0002746111,0.00004089046],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003286642,0.00001466418,0.0002320055,0.000006430243,0.0001387598,7.797113e-8,0.0002794374,8.827082e-7,0.9958203,0.000003210268,0.0006792165,0.00249639],"study_design_scores_gemma":[0.0001497455,0.0007028554,0.002444853,0.00004475802,0.00002198576,0.00004039427,0.0007898312,0.000007597496,0.9923884,0.00003868639,0.003308465,0.00006245964],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957721,0.001852371,0.00007289279,0.00213788,0.00001962671,0.0001146835,0.000001869007,0.000001877273,0.00002671011],"genre_scores_gemma":[0.9980502,0.0009541087,0.0003860014,0.0003152236,0.0002083518,0.000007073555,1.11839e-7,0.000009808514,0.00006911562],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003431893,"threshold_uncertainty_score":0.3294094,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008213420539032899,"score_gpt":0.2377286371842691,"score_spread":0.2295152166452362,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}