{"id":"W2786337140","doi":"10.1039/c8ra00707a","title":"Synthesis of novel cyclosiloxane monomers containing push–pull moieties and their anionic ring opening polymerization","year":2018,"lang":"en","type":"article","venue":"RSC Advances","topic":"Silicone and Siloxane Chemistry","field":"Materials Science","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Eidgenössische Materialprüfungs- und Forschungsanstalt; SCIEX; Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung; National Science Foundation","keywords":"Polymer chemistry; Monomer; Chemistry; Ring-opening polymerization; Anionic addition polymerization; Polymerization; Living anionic polymerization; Ring (chemistry); Cationic polymerization; Organic chemistry; Polymer","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000185395,0.0001453815,0.0002564391,0.00004327216,0.0001640955,0.00004692167,0.0001659961,0.00004933761,0.000107177],"category_scores_gemma":[0.000133152,0.0001242227,0.00002957636,0.0001056971,0.0002936893,0.0004565147,0.00008405219,0.00004664208,0.000004856275],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001772178,"about_ca_system_score_gemma":0.00002842072,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006305816,"about_ca_topic_score_gemma":0.00001053145,"domain_scores_codex":[0.9991212,0.00002004187,0.0002538051,0.0002779872,0.0001073713,0.0002195479],"domain_scores_gemma":[0.9993377,0.0001850846,0.0001887417,0.0001786321,0.00005606746,0.00005372788],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003867394,0.00001707359,0.002130879,0.00004141514,0.000007360275,3.813601e-7,0.0007246772,0.00004224341,0.9933571,0.0001487418,0.000001739451,0.003489693],"study_design_scores_gemma":[0.0002046899,0.00006194867,0.0005664843,0.0001125936,0.000008657111,0.000009226501,0.002712361,0.0003048215,0.9955733,0.00007887386,0.0002180857,0.000148935],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9946849,0.002093528,0.00112444,0.00004900553,0.0001440864,0.00007134353,0.00001760822,0.00004818633,0.001766889],"genre_scores_gemma":[0.9980013,0.0002341541,0.001530952,0.00003465485,0.0001200294,0.00001482761,0.000002496706,0.00001483795,0.0000467455],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003340758,"threshold_uncertainty_score":0.5065656,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01613720912669487,"score_gpt":0.2502647117151439,"score_spread":0.2341275025884491,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}