{"id":"W2786960829","doi":"10.1039/c7an01686g","title":"Selective determination of semi-volatile thiophene compounds in water by molecularly imprinted polymer thin films with direct headspace gas chromatography sulfur chemiluminescence detection","year":2018,"lang":"en","type":"article","venue":"The Analyst","topic":"Analytical chemistry methods development","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Natural Sciences and Engineering Research Council of Canada; Atlantic Canada Opportunities Agency","keywords":"Chemiluminescence; Chemistry; Thiophene; Gas chromatography; Chromatography; Molecularly imprinted polymer; Sulfur; Polymer; Molecular imprinting; Selectivity; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004064522,0.0002750976,0.0003843883,0.0000976764,0.0001145065,0.00003356014,0.0003322899,0.0001422411,0.0001951122],"category_scores_gemma":[0.00005561044,0.0001789934,0.0001110942,0.0007417123,0.0003203622,0.0001020765,0.00008806308,0.0002786709,0.000006521013],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001270976,"about_ca_system_score_gemma":0.00004535311,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005347134,"about_ca_topic_score_gemma":0.0001696523,"domain_scores_codex":[0.9983196,0.00008186734,0.0004094668,0.0004278965,0.0003951764,0.000366034],"domain_scores_gemma":[0.9988782,0.0001207211,0.0001951098,0.0004731881,0.0002529277,0.00007987711],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001449509,0.00007427185,0.004724925,0.0000663342,0.0001131605,0.00000340577,0.0006415779,0.000001636576,0.9940572,0.000001567915,0.0000252313,0.0001456908],"study_design_scores_gemma":[0.0004004702,0.00005090959,0.0005964257,0.00009647164,0.00009898472,0.00001607572,0.0002498644,0.005551661,0.9926161,0.00003806328,0.00003695466,0.0002480475],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9713057,0.00008639976,0.0217697,0.0001025851,0.00001478563,0.00009591129,0.000008042041,0.00006206951,0.00655484],"genre_scores_gemma":[0.9970166,0.000006979493,0.002175471,0.00003585775,0.00003604748,0.00003015866,0.00003936636,0.00003070088,0.0006288078],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02571094,"threshold_uncertainty_score":0.7299141,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00656799533831518,"score_gpt":0.235156784236125,"score_spread":0.2285887888978098,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}