{"id":"W2786960829","doi":"10.1039/c7an01686g","title":"Selective determination of semi-volatile thiophene compounds in water by molecularly imprinted polymer thin films with direct headspace gas chromatography sulfur chemiluminescence detection","year":2018,"lang":"en","type":"article","venue":"The Analyst","topic":"Analytical chemistry methods development","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Natural Sciences and Engineering Research Council of Canada; Atlantic Canada Opportunities Agency","keywords":"Chemiluminescence; Chemistry; Thiophene; Gas chromatography; Chromatography; Molecularly imprinted polymer; Sulfur; Polymer; Molecular imprinting; Selectivity; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004451355,0.001230453,0.0003825389,0.000759613,0.0003234769,0.0004752288,0.0008990788,0.0006023624,0.001780541],"category_scores_gemma":[0.000873577,0.0008218717,0.0004617797,0.0004990568,0.0006678731,0.0005824918,0.0006497874,0.0008889278,0.001246046],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004134791,"about_ca_system_score_gemma":0.0006262545,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007660507,"about_ca_topic_score_gemma":0.002421923,"domain_scores_codex":[0.9990277,0.000141099,0.00003331764,0.0002370375,0.0005118463,0.00004887396],"domain_scores_gemma":[0.9995815,0.0001555469,0.00008203604,0.00004165087,0.0001036571,0.0000356182],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002105382,0.000009726461,0.00009697003,0.00004187668,0.000008723617,0.0000238488,0.00001463592,0.00003213718,0.9964258,0.00004848,0.00005919412,0.003217638],"study_design_scores_gemma":[0.000005973772,0.00008382883,0.0008114578,0.000003488427,0.00001107702,0.0001647642,0.000009044072,0.001289538,0.9966596,0.00004174147,0.0009125104,0.000007101055],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.6244239,0.004906895,0.3546257,0.0004183712,0.0002884678,0.000684224,0.00145248,0.003086091,0.01011389],"genre_scores_gemma":[0.7419747,0.004489531,0.2374406,0.0003863817,0.00008859311,0.001014537,0.001296373,0.0003260584,0.01298319],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.001780541,"threshold_uncertainty_score":0.005956471,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00656799533831518,"score_gpt":0.235156784236125,"score_spread":0.2285887888978098,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}