{"id":"W2790273844","doi":"10.1039/c8dt00840j","title":"Versatile synthesis of chiral 6-oxoverdazyl radical ligands – new building blocks for multifunctional molecule-based magnets","year":2018,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"Agence Nationale de la Recherche; Natural Sciences and Engineering Research Council of Canada; Ontario Trillium Foundation","keywords":"Electron paramagnetic resonance; Isopropyl; Reactivity (psychology); Chemistry; Antiferromagnetism; Chelation; Molecule; Cyclic voltammetry; Crystallography; Pyridine; Stereochemistry; Medicinal chemistry; Organic chemistry; Nuclear magnetic resonance; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002559442,0.0001791148,0.0002416821,0.0001842932,0.0003261548,0.00005221916,0.0002648815,0.0001089291,0.01057347],"category_scores_gemma":[0.0001570681,0.0001882645,0.0001639393,0.0002468106,0.0002842183,0.0001746119,0.000008356857,0.00008945977,0.00004023611],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005798228,"about_ca_system_score_gemma":0.0002318793,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002381474,"about_ca_topic_score_gemma":0.00007926587,"domain_scores_codex":[0.9985128,0.00003898601,0.0003936958,0.0003836619,0.0003612681,0.0003095727],"domain_scores_gemma":[0.9986711,0.0005682029,0.0001349865,0.0002924041,0.0001775019,0.0001557638],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003651532,0.0002615027,0.00003634379,0.00007651384,0.0000269204,9.712614e-7,0.0001726788,0.001995072,0.971887,0.001182788,0.005630486,0.01836456],"study_design_scores_gemma":[0.001147437,0.0003575672,0.0003039151,0.00004065588,0.00008861186,0.000005652437,0.00002385458,0.02586886,0.9583926,0.00069554,0.01286189,0.0002134018],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.145811,0.00003357172,0.8499022,0.001158779,0.001131095,0.000394056,0.0004326822,0.0001480955,0.0009884931],"genre_scores_gemma":[0.9351755,0.000001941268,0.06334515,0.0001344103,0.000289881,0.0001044928,0.00001597647,0.00002616253,0.0009064851],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.7893645,"threshold_uncertainty_score":0.990331,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01960540103789838,"score_gpt":0.2655097542958229,"score_spread":0.2459043532579245,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}