{"id":"W2790927976","doi":"10.1002/chem.201801305","title":"Catalytic Hydrodefluorination of C−F Bonds by an Air‐Stable P<sup>III</sup> Lewis Acid","year":2018,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":62,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Catalysis; Lewis acids and bases; Reagent; Aryl; Medicinal chemistry; Organic chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001565764,0.0003790072,0.0003659656,0.00004853481,0.0004119053,0.00005530199,0.0009536628,0.0002184031,0.004056728],"category_scores_gemma":[0.0002545643,0.0003997092,0.0001298756,0.0002840488,0.0005811919,0.0003157636,0.0002218776,0.001538172,0.0002375066],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002084458,"about_ca_system_score_gemma":0.0001916148,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004037438,"about_ca_topic_score_gemma":3.605681e-7,"domain_scores_codex":[0.9974202,0.0003202864,0.0008100259,0.0004694012,0.0003416417,0.0006384239],"domain_scores_gemma":[0.9979124,0.00008499355,0.0004963625,0.0005342687,0.0003687909,0.0006031592],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001847944,0.0003824151,0.0004636491,0.0001124968,0.0001504908,0.0001510698,0.0008190399,0.0001719502,0.9394652,0.000005025463,0.0528518,0.005242045],"study_design_scores_gemma":[0.002125902,0.0001741278,0.00005913765,0.00003727345,0.0001423095,0.001204606,0.0002710728,0.005459514,0.8761249,0.00004070845,0.1140081,0.0003523955],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9473783,0.0005020166,0.0002576015,0.0003665438,0.000313103,0.00008945686,0.00008133356,0.0001090567,0.05090262],"genre_scores_gemma":[0.9869834,0.00009070164,0.0002268408,0.0003258439,0.002159694,0.000003025117,0.0001100048,0.00009396313,0.01000648],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06334036,"threshold_uncertainty_score":0.9998455,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04520426773327238,"score_gpt":0.3484815711777086,"score_spread":0.3032773034444363,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}