{"id":"W2791744095","doi":"10.1016/j.mcat.2018.02.012","title":"Mechanistic kinetics and reactor modelling of hydrogen production from the partial oxidation of diesel over a quartenary metal oxide catalyst","year":2018,"lang":"en","type":"article","venue":"Molecular Catalysis","topic":"Catalytic Processes in Materials Science","field":"Materials Science","cited_by":5,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Regina","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation; Faculty of Graduate Studies and Research, University of Regina","keywords":"Catalysis; Isothermal process; Chemistry; Diesel fuel; Partial oxidation; Partial pressure; Plug flow; Kinetics; Thermodynamics; Plug flow reactor model; Oxide; Hydrogen; Hexadecane; Rate equation; Chemical engineering; Physical chemistry; Continuous stirred-tank reactor; Organic chemistry; Oxygen","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006516775,0.0001730867,0.000335037,0.0000745477,0.00009171719,0.00004328795,0.0004233553,0.00006301775,0.00005602293],"category_scores_gemma":[0.0004225445,0.0001330543,0.00007783192,0.0003931204,0.0006030959,0.0002454197,0.0002210864,0.00004731254,0.00001644672],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003309531,"about_ca_system_score_gemma":0.00005249538,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001369003,"about_ca_topic_score_gemma":0.0000654617,"domain_scores_codex":[0.9981411,0.00008640899,0.0005072826,0.0005057848,0.0005414902,0.0002179349],"domain_scores_gemma":[0.9984566,0.00007836691,0.0004163111,0.0007554423,0.0002366956,0.00005660479],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004608779,0.00005759355,0.00002762108,0.00003600721,0.0000422484,0.000002440579,0.000615331,0.0005609038,0.9983771,0.0001516787,0.00000869492,0.00007426618],"study_design_scores_gemma":[0.0001144663,0.00007068418,0.00006313099,0.00003210377,0.0003678924,0.00000796153,0.0001204921,0.006778324,0.9906291,0.001657157,0.00001919481,0.0001394428],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9390046,0.0002423404,0.06016613,0.00008199373,0.0001913425,0.0001881435,0.00008365098,0.00002426813,0.00001751132],"genre_scores_gemma":[0.9966576,0.00001374335,0.00307236,0.00002357577,0.00009320554,0.00001920247,0.00009338531,0.00001785452,0.000009086433],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05765297,"threshold_uncertainty_score":0.5425798,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0173442691178981,"score_gpt":0.2325757505451454,"score_spread":0.2152314814272473,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}