{"id":"W2791870952","doi":"10.1002/anie.201800361","title":"Chemoselective Synthesis of <i>Z</i>‐Olefins through Rh‐Catalyzed Formate‐Mediated 1,6‐Reduction","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; University of Alberta","keywords":"Electrophile; Stereoselectivity; Formic acid; Chemistry; Catalysis; Formate; Medicinal chemistry; Functional group; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001448318,0.0001990051,0.0002367132,0.0001709108,0.0001069333,0.00003173851,0.0003025208,0.0001855892,0.003517997],"category_scores_gemma":[0.0005362779,0.0002038644,0.0001733172,0.0005117448,0.0001940283,0.0006001837,0.0000628819,0.0001414751,0.000180994],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002547009,"about_ca_system_score_gemma":0.0000643153,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001025343,"about_ca_topic_score_gemma":0.00001011087,"domain_scores_codex":[0.9983957,0.00001031474,0.0004598698,0.0003298522,0.0005894675,0.0002148263],"domain_scores_gemma":[0.9984281,0.0001276421,0.0003937664,0.0002370108,0.0007448788,0.0000685714],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001557193,0.0002857122,0.0002227511,0.00005407913,0.0004077978,0.000002057001,0.0006803214,0.00000291942,0.9836258,0.0003982897,0.01125151,0.002913043],"study_design_scores_gemma":[0.0005307307,0.00001479325,0.00007375266,0.00004978068,0.00008004248,0.00002637401,0.0004532029,0.000195101,0.9854024,0.0005574702,0.01241691,0.0001994642],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5599662,0.00013991,0.009794812,0.001352857,0.001790034,0.0001854275,0.001069132,0.0004095563,0.425292],"genre_scores_gemma":[0.9951901,0.0001269046,0.000342246,0.0001126638,0.001539954,0.00007600273,0.00198038,0.00002700371,0.0006047887],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4352238,"threshold_uncertainty_score":0.9973929,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01166991821873605,"score_gpt":0.250678147210368,"score_spread":0.2390082289916319,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}