{"id":"W2791941411","doi":"10.1007/s12678-018-0459-1","title":"Unfolding the Hidden Reactions in Galvanic Cells","year":2018,"lang":"en","type":"article","venue":"Electrocatalysis","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":false,"ca_institutions":"Collège Jean-de-Brébeuf; McGill University","funders":"","keywords":"Electromotive force; Galvanic cell; Pourbaix diagram; Enthalpy; Thermodynamics; Electrochemistry; Chemistry; Redox; Gibbs free energy; Electrochemical cell; Electrochemical potential; Aqueous solution; Entropy (arrow of time); Standard electrode potential; Standard molar entropy; Electrode; Physical chemistry; Inorganic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002955443,0.0003453399,0.0002684547,0.0001392503,0.0002751996,0.0008894361,0.0006025938,0.0005923985,0.001791501],"category_scores_gemma":[0.0005573879,0.0002335477,0.0002734707,0.0001470492,0.001044074,0.00134446,0.0005518876,0.001964366,0.0004645021],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003944553,"about_ca_system_score_gemma":0.0001920192,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002147851,"about_ca_topic_score_gemma":0.0002216238,"domain_scores_codex":[0.9998029,0.00004013877,0.000007240737,0.00004575531,0.00006332137,0.00004065427],"domain_scores_gemma":[0.999845,0.00006272271,0.00001526556,0.00004013066,0.0000213594,0.00001556219],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009776933,0.00008246346,0.0002435502,0.0001393562,0.00002201091,0.0001582081,0.0002191537,0.001803413,0.9416412,0.04093919,0.0004203639,0.01423324],"study_design_scores_gemma":[0.000007416161,0.00006393164,0.000264535,0.000007586515,0.000005592046,0.00007076878,0.00005092212,0.005431902,0.977557,0.01150843,0.005020034,0.00001189284],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8702835,0.003515488,0.1121681,0.001774223,0.0006531664,0.00005513413,0.0001358545,0.0004314837,0.01098307],"genre_scores_gemma":[0.9866323,0.001308392,0.006071307,0.0002722262,0.00005809073,0.0000254039,0.0001031677,0.00005766401,0.005471437],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001791501,"threshold_uncertainty_score":0.005993187,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006561062070811549,"score_gpt":0.2309690819705407,"score_spread":0.2244080198997292,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}