{"id":"W2792559554","doi":"10.1002/anie.201802090","title":"Nickel Fluorocarbene Metathesis with Fluoroalkenes","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Directorate for Mathematical and Physical Sciences; Welch Foundation","keywords":"Metathesis; Alkene; Carbene; Nickel; Trifluoromethyl; Chemistry; Salt metathesis reaction; Yield (engineering); Limiting; Organic chemistry; Medicinal chemistry; Catalysis; Materials science; Polymerization","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002485998,0.0002310002,0.0001802011,0.00007513932,0.0001566567,0.000035234,0.000387329,0.0002384493,0.009187971],"category_scores_gemma":[0.0001488129,0.0002089709,0.00008098251,0.0001673814,0.000330997,0.0002527145,0.00008901517,0.0003631347,0.0004970036],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001744598,"about_ca_system_score_gemma":0.00007645143,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002693962,"about_ca_topic_score_gemma":0.00001856628,"domain_scores_codex":[0.9986791,0.00003555317,0.0002695857,0.0003851085,0.0003371969,0.0002934358],"domain_scores_gemma":[0.9989314,0.0001878911,0.000144379,0.0002169594,0.0003696219,0.0001497559],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000410051,0.0002421099,0.002202515,0.00002430744,0.000468805,0.00003859622,0.0003277339,0.000007682232,0.9191467,0.0004131322,0.07135833,0.005360053],"study_design_scores_gemma":[0.0008972892,0.00008341534,0.000374096,0.00002073606,0.0001021158,0.0000960622,0.00009708652,0.0001150494,0.8299326,0.0003976392,0.167673,0.0002109634],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7969084,0.0004489186,0.002457785,0.008577861,0.007503906,0.000354322,0.0003071187,0.0005346005,0.1829071],"genre_scores_gemma":[0.9834846,0.0001076272,0.001057678,0.001550385,0.006547655,0.0000674547,0.000328878,0.0000409777,0.006814704],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1865763,"threshold_uncertainty_score":0.9917178,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05888518267335358,"score_gpt":0.380501401872374,"score_spread":0.3216162191990204,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}