{"id":"W2792559554","doi":"10.1002/anie.201802090","title":"Nickel Fluorocarbene Metathesis with Fluoroalkenes","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Directorate for Mathematical and Physical Sciences; Welch Foundation","keywords":"Metathesis; Alkene; Carbene; Nickel; Trifluoromethyl; Chemistry; Salt metathesis reaction; Yield (engineering); Limiting; Organic chemistry; Medicinal chemistry; Catalysis; Materials science; Polymerization","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001062695,0.0002923456,0.0001643874,0.0001865739,0.0001669612,0.0002073698,0.0002365112,0.0003192773,0.002643473],"category_scores_gemma":[0.0002114603,0.0001224232,0.0002022634,0.0001343023,0.0001285113,0.0002812092,0.0002603591,0.0003960952,0.0006015724],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003848627,"about_ca_system_score_gemma":0.0002214964,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004673556,"about_ca_topic_score_gemma":0.0009671292,"domain_scores_codex":[0.9998852,0.00001642173,0.000006708376,0.0000228131,0.00002973347,0.00003914038],"domain_scores_gemma":[0.9999588,0.000008406962,0.000008823707,0.00001054518,0.000005349547,0.000008056389],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001703144,0.00004206762,0.0001971608,0.0001620395,0.00001872748,0.0003468113,0.00009204839,0.0008911385,0.9844736,0.003377655,0.0003421613,0.009886243],"study_design_scores_gemma":[0.0000097128,0.0001601756,0.0003243833,0.00000662916,0.000006366634,0.0001428701,0.00001090961,0.0006237735,0.9941491,0.000149355,0.004411587,0.000005146293],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9543683,0.00246237,0.01032055,0.0002607596,0.00009958595,0.00008988102,0.0003079269,0.0003127295,0.03177799],"genre_scores_gemma":[0.994494,0.0005451006,0.001880516,0.00002721467,0.000006602287,0.00001488873,0.00008122738,0.00001890019,0.002931474],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002643473,"threshold_uncertainty_score":0.008843303,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05888518267335358,"score_gpt":0.380501401872374,"score_spread":0.3216162191990204,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}