{"id":"W2793301999","doi":"10.1016/j.jorganchem.2017.12.043","title":"Oxygen atom transfer to platinum(II): A 2-pyridyloxaziridine and a 2-pyridylnitrone as potential oxygen atom donors","year":2018,"lang":"en","type":"article","venue":"Journal of Organometallic Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":false,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Medicinal chemistry; Ligand (biochemistry); Methanol; Platinum; Oxygen; Oxygen atom; Solvent; Stereochemistry; Photochemistry; Molecule; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0007016962,0.0006687334,0.001007272,0.0002558631,0.0003750425,0.0001838827,0.0009609293,0.0004299903,0.02306924],"category_scores_gemma":[0.0002348488,0.0006350178,0.0004385404,0.0006999611,0.0002464449,0.0004184595,0.0003559685,0.000731123,0.0001978203],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002803369,"about_ca_system_score_gemma":0.0003948846,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000181479,"about_ca_topic_score_gemma":0.000005841319,"domain_scores_codex":[0.9957885,0.00003648303,0.001520052,0.0007238683,0.001181048,0.000750042],"domain_scores_gemma":[0.9970379,0.00007630048,0.0004375157,0.0007435928,0.0006865636,0.001018099],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000386838,0.0002402184,0.00006078445,0.0002000141,0.0005783982,0.0001420937,0.0007436281,0.00001162461,0.9954886,0.0001098893,0.0008151725,0.001222775],"study_design_scores_gemma":[0.002758119,0.0001955469,0.0001943199,0.0001209653,0.0003811644,0.002113187,0.0005302757,0.00006788134,0.9496239,0.0005423661,0.04280304,0.0006692258],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.990972,0.0005318246,0.003441832,0.001057693,0.0002711635,0.0001605459,0.0001278727,0.00008266737,0.003354333],"genre_scores_gemma":[0.9889134,0.0001508814,0.003750582,0.000331528,0.002024049,0.00001447936,0.00007560965,0.0001482564,0.004591272],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04586465,"threshold_uncertainty_score":0.9996101,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009968568084938987,"score_gpt":0.2311286888815665,"score_spread":0.2211601207966275,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}