{"id":"W2793768337","doi":"10.1002/cplu.201800045","title":"Hexaethylbenzene: A Sterically Crowded Arene and Conformationally Versatile Ligand","year":2018,"lang":"en","type":"review","venue":"ChemPlusChem","topic":"Dendrimers and Hyperbranched Polymers","field":"Materials Science","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; University College Dublin; Science Foundation Ireland","keywords":"Steric effects; Ligand (biochemistry); Chemistry; Stereochemistry; Combinatorial chemistry; Nanotechnology; Materials science","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0003331364,0.0005140529,0.001346885,0.0001110379,0.0001714834,0.0002680204,0.000465993,0.0003934166,0.0009402134],"category_scores_gemma":[0.00007090092,0.0004239978,0.0002511815,0.0001881274,0.0002993261,0.000247595,0.0002743211,0.0002325125,0.001051239],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007484301,"about_ca_system_score_gemma":0.0003879904,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001372144,"about_ca_topic_score_gemma":0.000005008417,"domain_scores_codex":[0.9978679,0.00005419778,0.0006890827,0.0005777983,0.0003519783,0.000459077],"domain_scores_gemma":[0.9985746,0.0001509384,0.0004260308,0.000495577,0.0001004339,0.0002524318],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000151791,0.0002912554,0.00001112634,0.05916851,0.0007921261,0.0001016794,0.003826172,3.980215e-7,0.02781421,0.001626249,0.07409041,0.8321261],"study_design_scores_gemma":[0.0003236964,0.00005157448,0.000002408776,0.001921962,0.0002797472,0.00007275746,0.00002040074,0.000002758482,0.01149509,0.00002839146,0.985299,0.0005022225],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.002324138,0.9873218,0.00003278133,0.00003564433,0.0005427122,0.0003850516,0.0001375143,0.0001026792,0.009117663],"genre_scores_gemma":[0.0001673823,0.9957936,0.001123082,0.0002088434,0.0005063401,0.00008441728,0.0001867996,0.00007647538,0.001853001],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.9112086,"threshold_uncertainty_score":0.9999731,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04117266474203867,"score_gpt":0.3073865078542759,"score_spread":0.2662138431122372,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}