{"id":"W2793988675","doi":"10.1002/anie.201800144","title":"Heteroleptic Copper(I)‐Based Complexes for Photocatalysis: Combinatorial Assembly, Discovery, and Optimization","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":178,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Copper; Modularity (biology); Photocatalysis; Catalysis; Combinatorial chemistry; Chemistry; BINAP; Materials science; Enantioselective synthesis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009013571,0.0001912297,0.0001864236,0.00007293453,0.000156568,0.0001735283,0.0002133813,0.0001625319,0.0005441534],"category_scores_gemma":[0.0003947411,0.0001967472,0.00011868,0.00008820106,0.0002970698,0.0004673633,0.00004880143,0.000135381,0.00001248063],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002014836,"about_ca_system_score_gemma":0.00004418738,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003737581,"about_ca_topic_score_gemma":0.000007053464,"domain_scores_codex":[0.9987164,0.000006871301,0.0003045827,0.0003940188,0.000366707,0.0002114429],"domain_scores_gemma":[0.9989464,0.000265307,0.0001638244,0.0001960807,0.0003113302,0.0001170037],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002904802,0.0002305354,0.00009045002,0.00005895019,0.0001154055,0.000001178698,0.00003689949,0.0001773351,0.9846702,0.0006081827,0.01357466,0.0001457008],"study_design_scores_gemma":[0.00161658,0.00005815825,0.00001709571,0.00008355575,0.00006674515,0.000006544187,0.00003281967,0.02159076,0.9661486,0.001601277,0.008570462,0.0002073781],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.4124039,0.0001128729,0.5231918,0.004942189,0.00644054,0.00130932,0.002458625,0.000722069,0.04841873],"genre_scores_gemma":[0.9915273,0.00001411296,0.001693566,0.0002980293,0.002846153,0.0003036422,0.003043894,0.00003237985,0.0002409399],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.5791234,"threshold_uncertainty_score":0.8023117,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01625448047705976,"score_gpt":0.2783640413260986,"score_spread":0.2621095608490389,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}