{"id":"W2794201173","doi":"10.1002/chem.201801012","title":"An Alumino‐Mannich Reaction of Organoaluminum Reagents, Silylated Amines, and Aldehydes","year":2018,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Ministère de l’Éducation, Gouvernement de l’Ontario; University of Toronto","keywords":"Iminium; Reagent; Mannich reaction; Chemistry; Organic chemistry; Component (thermodynamics); Combinatorial chemistry; Ion; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003546155,0.0005717457,0.0001811595,0.0003864775,0.0002888809,0.0002286167,0.0003586002,0.0002473972,0.001702277],"category_scores_gemma":[0.0002126003,0.0002402689,0.0002647672,0.0001973477,0.0002358525,0.0004014627,0.0004207767,0.0005043261,0.0005463119],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003325789,"about_ca_system_score_gemma":0.0003094235,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004664024,"about_ca_topic_score_gemma":0.001156244,"domain_scores_codex":[0.9998068,0.000035385,0.00001573966,0.00003885126,0.00004343942,0.00005981881],"domain_scores_gemma":[0.9999015,0.00001817446,0.00002321166,0.00001628671,0.00001399294,0.00002684083],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001149384,0.00002072857,0.0001871332,0.00008350587,0.00001709979,0.000126863,0.0000636953,0.0001324137,0.9925417,0.001499923,0.00008776691,0.005124168],"study_design_scores_gemma":[0.000008820239,0.0001721805,0.0004520286,0.000004375263,0.00001277598,0.0002725543,0.00001459888,0.0002555788,0.9952322,0.0001245316,0.003443513,0.000006834687],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9361848,0.001934839,0.03904169,0.0001833434,0.0001429598,0.0001329465,0.0001370082,0.0004710048,0.02177141],"genre_scores_gemma":[0.9849591,0.0005932035,0.008061498,0.00003322184,0.00001495704,0.00002992092,0.0001081054,0.00002955342,0.006170417],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001702277,"threshold_uncertainty_score":0.005694687,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01153795025156972,"score_gpt":0.2243921053799912,"score_spread":0.2128541551284215,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}