{"id":"W2794292031","doi":"10.1002/chem.201800593","title":"Release of Isonitrile‐ and NHC‐Stabilized Borylenes from Group VI Terminal Borylene Complexes","year":2018,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Deutscher Akademischer Austauschdienst; Deutsche Forschungsgemeinschaft; Department of Science and Technology, Ministry of Science and Technology, India; Alexander von Humboldt-Stiftung","keywords":"Terphenyl; Chemistry; Carbene; Medicinal chemistry; Stereochemistry; Leaving group; Electrophile; Catalysis; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001063124,0.0003424927,0.0002217652,0.0001027578,0.00008623503,0.0002078764,0.0002200711,0.0001885555,0.0010679],"category_scores_gemma":[0.0001326596,0.0001359028,0.0001789751,0.0001051242,0.0001463883,0.0002017257,0.0001529212,0.0002489366,0.0002318977],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002033484,"about_ca_system_score_gemma":0.0001142548,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003067995,"about_ca_topic_score_gemma":0.000454503,"domain_scores_codex":[0.9999226,0.000008031641,0.000005296858,0.00001855814,0.00002062044,0.00002489407],"domain_scores_gemma":[0.9999468,0.000006812124,0.00001766989,0.000007307353,0.000006932464,0.00001454874],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001268895,0.00001198994,0.00006639203,0.00003687292,0.000005493093,0.00004062289,0.00002088279,0.0001344428,0.9982293,0.0001203846,0.00002905988,0.001177667],"study_design_scores_gemma":[0.00001619424,0.0002317548,0.0004675897,0.000002039057,0.000006181064,0.00004009665,0.000006278809,0.0003616211,0.9981083,0.000008735997,0.0007482702,0.000003076172],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966846,0.0003602116,0.001178964,0.00001913136,0.000009028761,0.00001668555,0.0001111288,0.00003574188,0.001584524],"genre_scores_gemma":[0.9967506,0.0002576159,0.0009878568,0.000009769174,0.000002814394,0.0000107514,0.0001760342,0.00002458834,0.001779901],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0010679,"threshold_uncertainty_score":0.003572524,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01247920026837437,"score_gpt":0.2261290748162783,"score_spread":0.213649874547904,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}