{"id":"W2794664331","doi":"10.3390/molecules23040786","title":"ω-Methylsulfanylalkyl Glucosinolates: A General Synthetic Pathway","year":2018,"lang":"en","type":"article","venue":"Molecules","topic":"Genomics, phytochemicals, and oxidative stress","field":"Biochemistry, Genetics and Molecular Biology","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Laurentian University","funders":"Université d'Orléans","keywords":"Moiety; Chemistry; Sulfation; Stereochemistry; Homogeneous; Nitronate; Combinatorial chemistry; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009868993,0.0002343243,0.0001774481,0.00004557315,0.0001192375,0.00004037043,0.0003159119,0.0001668692,0.00005834187],"category_scores_gemma":[0.0001021971,0.0002239504,0.000127893,0.00008036882,0.0003028589,0.000003189559,0.0001770547,0.00008680786,0.0001338333],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001531255,"about_ca_system_score_gemma":0.00005780993,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001817161,"about_ca_topic_score_gemma":0.00002021737,"domain_scores_codex":[0.998686,0.00006504964,0.0002169208,0.0005231743,0.0001220246,0.0003868154],"domain_scores_gemma":[0.9991301,0.000009075703,0.00007884647,0.00051991,0.0001375077,0.0001246111],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005370387,0.00005460697,0.0003401353,0.000009046078,0.0000465956,0.000004232094,0.000063528,0.000005462824,0.9939349,0.0002909952,0.00160748,0.003589356],"study_design_scores_gemma":[0.0003335271,0.0002648243,0.001014258,0.00001305929,0.00001345889,0.00001331057,0.00003632467,0.00007540856,0.9472501,0.0006629918,0.05003669,0.0002860326],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9853545,0.001178736,0.005501419,0.0001455087,0.0002310695,0.0001567882,0.00004814355,0.00003095429,0.007352825],"genre_scores_gemma":[0.9930044,0.00007842212,0.004185766,0.0006686597,0.0008058728,0.00002754131,0.00009872506,0.00004388999,0.001086672],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04842922,"threshold_uncertainty_score":0.9132434,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008039644315229315,"score_gpt":0.2359903986377233,"score_spread":0.2279507543224939,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}