{"id":"W2794664331","doi":"10.3390/molecules23040786","title":"ω-Methylsulfanylalkyl Glucosinolates: A General Synthetic Pathway","year":2018,"lang":"en","type":"article","venue":"Molecules","topic":"Genomics, phytochemicals, and oxidative stress","field":"Biochemistry, Genetics and Molecular Biology","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Laurentian University","funders":"Université d'Orléans","keywords":"Moiety; Chemistry; Sulfation; Stereochemistry; Homogeneous; Nitronate; Combinatorial chemistry; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002281009,0.0005869007,0.0002812049,0.0003257556,0.0002393975,0.0002535412,0.0003765526,0.0003876337,0.002128121],"category_scores_gemma":[0.0001436322,0.0002052275,0.0002960102,0.0003113502,0.000195555,0.0003291756,0.0003925197,0.0006241145,0.001714919],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002542599,"about_ca_system_score_gemma":0.0007199778,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005257251,"about_ca_topic_score_gemma":0.00078034,"domain_scores_codex":[0.9998637,0.00002189482,0.00001527855,0.0000354095,0.00002454912,0.00003910223],"domain_scores_gemma":[0.9999043,0.000008475266,0.00001561739,0.00001983192,0.00002777377,0.00002401858],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001185301,0.00005415459,0.0001558609,0.000192599,0.00001169685,0.000252144,0.00006561873,0.0004819127,0.9872125,0.002087825,0.0002583071,0.009108926],"study_design_scores_gemma":[0.00005496305,0.0006949303,0.0006698397,0.00001952973,0.00002823083,0.0006915131,0.00004035647,0.0007608222,0.9697807,0.0006346413,0.0265926,0.0000320131],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7864897,0.00344459,0.1731548,0.0009097981,0.0003319817,0.001397468,0.004081103,0.001620659,0.02856985],"genre_scores_gemma":[0.9032001,0.004437414,0.07888725,0.0002344452,0.00004989147,0.0004380076,0.001829266,0.0001247298,0.01079895],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002128121,"threshold_uncertainty_score":0.007119298,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008039644315229315,"score_gpt":0.2359903986377233,"score_spread":0.2279507543224939,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}