{"id":"W2795938000","doi":"10.1021/jacs.8b00995","title":"Evidence for Redox Mechanisms in Organometallic Chemisorption and Reactivity on Sulfated Metal Oxides","year":2018,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Zeolite Catalysis and Synthesis","field":"Chemistry","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Government of Canada; Argonne National Laboratory; Basic Energy Sciences; National Energy Research Scientific Computing Center; U.S. Department of Energy","keywords":"Chemistry; Redox; Chemisorption; Reactivity (psychology); Organometallic chemistry; Catalysis; Non-innocent ligand; Inorganic chemistry; Metal; Photochemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001828306,0.0002444203,0.0001300344,0.0003193232,0.0001282469,0.0003447468,0.0004453179,0.0002727045,0.0007015935],"category_scores_gemma":[0.0003313377,0.0001891553,0.0002211508,0.0001386296,0.0004504712,0.0002866903,0.0002070866,0.0002536565,0.0001132152],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002349243,"about_ca_system_score_gemma":0.000117162,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004948133,"about_ca_topic_score_gemma":0.0006749533,"domain_scores_codex":[0.9998955,0.0000108265,0.000008427605,0.00002258114,0.00004600261,0.00001670808],"domain_scores_gemma":[0.9998609,0.00005630576,0.00003331872,0.00001692018,0.00002078889,0.00001181537],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001413279,0.00003567441,0.003415358,0.0001239523,0.00002219572,0.0001286545,0.0000628113,0.0006485736,0.9919384,0.00113833,0.00003186855,0.002312816],"study_design_scores_gemma":[0.00001632039,0.0001626339,0.008462117,0.000005637046,0.00001926876,0.0001479459,0.00008288155,0.005721618,0.9841829,0.0005441832,0.0006454376,0.000009169572],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978659,0.0004343312,0.0008598814,0.00004407669,0.000004780596,0.000004225122,0.00003983832,0.00001215351,0.0007348754],"genre_scores_gemma":[0.9991789,0.0002143243,0.0003768736,0.000007488668,0.000002661566,0.000001831077,0.00004350327,0.000001821564,0.0001726406],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007015935,"threshold_uncertainty_score":0.002347112,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03309825004218431,"score_gpt":0.2808199111113205,"score_spread":0.2477216610691362,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}