{"id":"W2796311527","doi":"10.1039/c8dt01154k","title":"The pivotal role of electronics in preferred alkene over alkyne Ni–carboryne insertions and absolute regioselectivities","year":2018,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"National Natural Science Foundation of China","keywords":"Alkyne; Alkene; Absolute configuration; Absolute (philosophy); Chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001950696,0.0003685057,0.0001604393,0.0001470464,0.0001538231,0.0005974174,0.0004279093,0.0002349312,0.003130174],"category_scores_gemma":[0.0005710138,0.000177304,0.0001647678,0.0001452044,0.0002978653,0.0005827761,0.0003470034,0.000493506,0.0004691969],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003111683,"about_ca_system_score_gemma":0.0001904672,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000418278,"about_ca_topic_score_gemma":0.0009627513,"domain_scores_codex":[0.9998645,0.00001089606,0.000009881395,0.00003557511,0.00003050385,0.00004865784],"domain_scores_gemma":[0.9998463,0.00006750114,0.00002787169,0.00002066483,0.0000244048,0.00001317578],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002722892,0.00004632002,0.001196584,0.0004179646,0.0000216892,0.0002789137,0.0002106729,0.002230309,0.9738402,0.008325558,0.0002176325,0.01294186],"study_design_scores_gemma":[0.000005907993,0.00009929469,0.001262664,0.00001194987,0.00001298203,0.0001155481,0.00008690098,0.003561807,0.9923914,0.0004525045,0.00198974,0.000009218378],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9821954,0.0008854253,0.00436597,0.00006734293,0.00002222192,0.0000243528,0.0002099308,0.0001173668,0.01211197],"genre_scores_gemma":[0.9977679,0.000299089,0.0009358579,0.000008169285,0.000001608077,0.0000125782,0.00008435028,0.00001626594,0.0008740959],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003130174,"threshold_uncertainty_score":0.01047146,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006386421383832491,"score_gpt":0.2173450636071352,"score_spread":0.2109586422233027,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}