{"id":"W2799502015","doi":"10.1007/s10337-018-3534-0","title":"Chiral Separations Using a Modified Water Stationary Phase in Supercritical Fluid Chromatography","year":2018,"lang":"en","type":"article","venue":"Chromatographia","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Supercritical fluid chromatography; Chromatography; Enantiomer; Elution; Analyte; Phase (matter); Supercritical fluid; Resolution (logic); Chiral column chromatography; High-performance liquid chromatography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000177954,0.0005164575,0.0005393224,0.0005532709,0.0004334928,0.0001259352,0.0004500568,0.0003737093,0.005026381],"category_scores_gemma":[0.00003313099,0.0004605482,0.0004758147,0.001242267,0.001267865,0.0004236851,0.0001199904,0.0003755335,0.0001023673],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004592929,"about_ca_system_score_gemma":0.00008146521,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005772947,"about_ca_topic_score_gemma":0.00002528731,"domain_scores_codex":[0.9967692,0.00004646073,0.0008470371,0.000805813,0.0004947477,0.001036736],"domain_scores_gemma":[0.9986312,0.00007566025,0.00003902329,0.0007009376,0.0001516712,0.0004014435],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001716119,0.001324427,0.008877317,0.0002780469,0.0002034033,0.0001346688,0.0006536549,0.00002473999,0.9825929,0.004587916,0.001085076,0.00006620942],"study_design_scores_gemma":[0.005965877,0.0002065984,0.0007377294,0.0003210478,0.0002405792,0.0003126143,0.001074041,0.03136402,0.9471516,0.008658161,0.002457154,0.001510596],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9730808,0.0001751333,0.0006879943,0.0001094623,0.00009705233,0.0001369768,0.0001109089,0.000320876,0.02528086],"genre_scores_gemma":[0.9980244,0.00002474103,0.0008164737,0.0001663035,0.0003947548,0.00006040419,0.0003777888,0.00006989467,0.00006524484],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03544134,"threshold_uncertainty_score":0.9997846,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02521355014022682,"score_gpt":0.309841532233584,"score_spread":0.2846279820933572,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}