{"id":"W2800224276","doi":"10.1002/bio.3492","title":"Effect of viscosity and dielectric constant variation on fractional fluorescence quenching analysis of coumarin dye in binary solvent mixtures","year":2018,"lang":"en","type":"article","venue":"Luminescence","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":43,"is_retracted":false,"has_abstract":true,"ca_institutions":"Horizon College and Seminary","funders":"","keywords":"Acetonitrile; Quenching (fluorescence); Chemistry; Viscosity; Solvent; Fluorescence; Dielectric; Excited state; Conformational isomerism; Analytical Chemistry (journal); Intramolecular force; Photochemistry; Molecule; Thermodynamics; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000229685,0.0001467655,0.0003498367,0.0001348849,0.00007050052,0.00000648787,0.0001141265,0.00007641994,0.00006871585],"category_scores_gemma":[0.0001355573,0.0001312676,0.0000710508,0.0005716769,0.0001931215,0.00005948231,0.00002703078,0.0001628935,4.27381e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005596423,"about_ca_system_score_gemma":0.00003331851,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003703641,"about_ca_topic_score_gemma":0.00006964862,"domain_scores_codex":[0.9990201,0.00003867555,0.0002724888,0.0002750028,0.0002130235,0.0001807301],"domain_scores_gemma":[0.9992931,0.0003141456,0.0001187695,0.0001733811,0.0000675076,0.00003312042],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005019376,0.0001247683,0.08276223,0.0002493401,0.0001915484,0.000003828454,0.0002921591,0.0000243835,0.9152223,0.00007791616,0.000007876391,0.0005416942],"study_design_scores_gemma":[0.0003571713,0.000276983,0.05188251,0.0001455242,0.000229888,0.000002053454,0.00001421866,0.00522586,0.9417231,0.00002892876,0.000002920007,0.0001108592],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982148,0.0001664057,0.0002731454,0.00002449312,0.00002353989,0.00007085615,0.00002012011,0.00001271973,0.001193955],"genre_scores_gemma":[0.9997677,0.00009680512,0.00004001561,0.00000872666,0.00002708768,0.00002145955,0.00001437091,0.000004498219,0.0000193743],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03087972,"threshold_uncertainty_score":0.5352939,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005624092572672388,"score_gpt":0.2509314784074583,"score_spread":0.245307385834786,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}