{"id":"W2800324893","doi":"10.1002/cphc.201800371","title":"<i>Endo</i> or <i>Exo</i>? Structures of Gas‐Phase Alkali Metal Cation/Aromatic Half‐Belt Complexes","year":2018,"lang":"en","type":"article","venue":"ChemPhysChem","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Natural Sciences and Engineering Research Council of Canada; Western Canada Research Grid","keywords":"Chemistry; Infrared multiphoton dissociation; Fourier transform ion cyclotron resonance; Dissociation (chemistry); Mass spectrum; Molecule; Population; Infrared spectroscopy; Ion; Ionic bonding; Alkali metal; Infrared; Bond-dissociation energy; Mass spectrometry; Analytical Chemistry (journal); Physical chemistry; Crystallography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006125755,0.0002368066,0.0001539649,0.0001284061,0.0002520863,0.0003287632,0.0004975912,0.0002690948,0.002978047],"category_scores_gemma":[0.0001328476,0.0001153363,0.0001032682,0.0001163596,0.0002662983,0.0002718719,0.0002480631,0.0002438247,0.0001928381],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003127583,"about_ca_system_score_gemma":0.0001027069,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006640523,"about_ca_topic_score_gemma":0.0003878237,"domain_scores_codex":[0.999964,0.000003893276,0.0000016839,0.000009867828,0.000008508897,0.00001207526],"domain_scores_gemma":[0.9999532,0.000009632621,0.00001847016,0.000005246058,0.000004801898,0.000008729279],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001497444,0.0001074611,0.005251139,0.0003845635,0.00006122076,0.0005887613,0.0003795265,0.0100592,0.9573686,0.0158561,0.0009703673,0.007475648],"study_design_scores_gemma":[0.0004221309,0.001736692,0.02778083,0.00005228021,0.00009169304,0.001011009,0.001123363,0.1409288,0.8108014,0.006885921,0.009052032,0.0001138724],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.997823,0.0001038118,0.0006605851,0.00003025535,0.000003655091,0.000004187443,0.00006450801,0.00002593847,0.001284117],"genre_scores_gemma":[0.9991386,0.00003492046,0.0003167573,0.00001175892,9.180596e-7,0.000006694295,0.0001207655,0.000009353755,0.0003602279],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002978047,"threshold_uncertainty_score":0.009962618,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02093063624391187,"score_gpt":0.2751385955898609,"score_spread":0.254207959345949,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}