{"id":"W2800741041","doi":"10.1002/anie.201800636","title":"Another Unprecedented Wieland Mechanism Confirmed: Hydrogen Formation from Hydrogen Peroxide, Formaldehyde, and Sodium Hydroxide","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Catalysis and Oxidation Reactions","field":"Chemical Engineering","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"Narodowym Centrum Nauki; Narodowe Centrum Nauki","keywords":"Chemistry; Deprotonation; Kinetic isotope effect; Hydrogen peroxide; Concerted reaction; Formaldehyde; Photochemistry; Formate; Deuterium; Hydrogen; Reaction mechanism; Inorganic chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002112096,0.0003761173,0.000335661,0.0003418584,0.0005181138,0.0006920542,0.0007967167,0.0007720914,0.003921439],"category_scores_gemma":[0.000278792,0.0003366805,0.0003573527,0.0001187678,0.0006894022,0.001563312,0.0008056731,0.0008082672,0.0005340211],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004292723,"about_ca_system_score_gemma":0.0002337352,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004019545,"about_ca_topic_score_gemma":0.0003618259,"domain_scores_codex":[0.9998782,0.00001313174,0.000005298896,0.00004035451,0.00002834306,0.00003470985],"domain_scores_gemma":[0.9999275,0.00002019933,0.00001388783,0.00001788174,0.0000085195,0.00001203505],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006034498,0.0002709116,0.00443298,0.0007361576,0.0001890591,0.002553718,0.000530231,0.006478716,0.7243091,0.2336271,0.003439065,0.02282955],"study_design_scores_gemma":[0.0002051746,0.0007146314,0.002769804,0.00005216528,0.00008664619,0.001203481,0.0003143326,0.04043529,0.8780914,0.0506038,0.02541439,0.0001089276],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8877462,0.005360724,0.06303634,0.001520274,0.00126132,0.0001578311,0.00029428,0.000731587,0.0398915],"genre_scores_gemma":[0.9914835,0.0005110842,0.004692485,0.0001077137,0.00002802534,0.00002953377,0.0000588913,0.00001473004,0.003073954],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003921439,"threshold_uncertainty_score":0.01311857,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.012254296989532,"score_gpt":0.2349470856985043,"score_spread":0.2226927887089723,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}