{"id":"W2801445913","doi":"10.1002/poc.3838","title":"The history and triumph of physical organic chemistry","year":2018,"lang":"en","type":"article","venue":"Journal of Physical Organic Chemistry","topic":"History and advancements in chemistry","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Faraday cage; History of chemistry; Physical organic chemistry; Bioorganic chemistry; Nanotechnology; Polymer science; Organic chemistry; Astrobiology; Epistemology; History of science; Magnetic field; Philosophy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.002508855,0.0003168167,0.0003823577,0.001419673,0.00180602,0.004015271,0.0005572423,0.001482809,0.006987799],"category_scores_gemma":[0.003105529,0.0002751757,0.000180953,0.001426102,0.007944023,0.004650737,0.002295931,0.004100196,0.001860472],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.003178799,"about_ca_system_score_gemma":0.002034515,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001252178,"about_ca_topic_score_gemma":0.00105918,"domain_scores_codex":[0.9987134,0.0004235237,0.00005161233,0.0002080761,0.0004640563,0.0001392951],"domain_scores_gemma":[0.9979242,0.001052603,0.000133611,0.0002284153,0.0003893618,0.0002718502],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0001164814,0.00009405817,0.0007743609,0.0007963167,0.00001448443,0.0002491063,0.001718088,0.000236647,0.00213556,0.7331241,0.07957493,0.1811659],"study_design_scores_gemma":[0.000006124152,0.00003836794,0.000472681,0.0003855818,0.00000257005,0.0001271776,0.0002883229,0.0001166672,0.0006648293,0.07375212,0.9241319,0.00001362541],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.01572438,0.6582599,0.004998003,0.103979,0.02022089,0.00003789554,0.0002266724,0.0001133361,0.1964398],"genre_scores_gemma":[0.2868995,0.5680401,0.004923709,0.02877521,0.02657563,0.0001091457,0.0001911973,0.0001822851,0.08430313],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.006987799,"threshold_uncertainty_score":0.02337652,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007326785636648511,"score_gpt":0.2300034453094899,"score_spread":0.2226766596728413,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}