{"id":"W2801445913","doi":"10.1002/poc.3838","title":"The history and triumph of physical organic chemistry","year":2018,"lang":"en","type":"article","venue":"Journal of Physical Organic Chemistry","topic":"History and advancements in chemistry","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Faraday cage; History of chemistry; Physical organic chemistry; Bioorganic chemistry; Nanotechnology; Polymer science; Organic chemistry; Astrobiology; Epistemology; History of science; Magnetic field; Philosophy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002415665,0.0004105312,0.0007001825,0.00001334072,0.0002186918,0.00002679118,0.0008594161,0.0002077288,0.005203282],"category_scores_gemma":[0.0005691258,0.0003200777,0.0003600646,0.0001682841,0.001314631,0.0001765235,0.0002233786,0.0009721444,0.0000165054],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006523764,"about_ca_system_score_gemma":0.0004939574,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001050423,"about_ca_topic_score_gemma":2.907128e-7,"domain_scores_codex":[0.9976664,0.00002022878,0.0007719126,0.0003912742,0.0007098087,0.0004403327],"domain_scores_gemma":[0.9969978,0.0004535463,0.001098396,0.0006898177,0.0004345738,0.0003258209],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001575316,0.0005025381,0.00004129046,0.0004789963,0.0001784958,0.00002146552,0.0006386434,7.469089e-7,0.9934385,0.00001657551,0.002354651,0.002170508],"study_design_scores_gemma":[0.001113834,0.00007019742,0.000009722498,0.0001487914,0.0001643353,0.0001484632,0.000363024,0.00007604138,0.8953502,0.0003694661,0.1018892,0.0002968342],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9761336,0.001249303,0.00003158396,0.0001371245,0.0002103246,0.00003252926,0.00001589942,0.00003437118,0.02215528],"genre_scores_gemma":[0.9825726,0.00008728716,0.000057437,0.00004108359,0.004049293,0.000002764006,0.000005274044,0.0000660018,0.01311823],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09953451,"threshold_uncertainty_score":0.9999251,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007326785636648511,"score_gpt":0.2300034453094899,"score_spread":0.2226766596728413,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}