{"id":"W2801703537","doi":"10.1063/1.5016452","title":"Excited state non-adiabatic dynamics of the smallest polyene, <i>trans</i> 1,3-butadiene. I. Time-resolved photoelectron-photoion coincidence spectroscopy","year":2018,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada; University of Ottawa","funders":"U.S. Department of Energy","keywords":"Excited state; Conical intersection; Atomic physics; Chemistry; Ionization; Spectroscopy; Wave packet; Adiabatic process; Molecular physics; Physics; Ion; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007462651,0.0001806289,0.00009771735,0.0002118759,0.0002760974,0.0002935634,0.0001866051,0.000167023,0.001200778],"category_scores_gemma":[0.0003061771,0.0001140839,0.00008142641,0.0001893025,0.000270944,0.000481216,0.0001937642,0.0004392034,0.0001036384],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003278689,"about_ca_system_score_gemma":0.0001542692,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008524432,"about_ca_topic_score_gemma":0.0006536813,"domain_scores_codex":[0.9999443,0.000004456111,0.000001300416,0.00001775448,0.00001625974,0.00001588165],"domain_scores_gemma":[0.9998798,0.00004417732,0.00003534667,0.0000108922,0.00001500464,0.00001464236],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002222344,0.00005223546,0.005811832,0.00005698962,0.00001123413,0.000329786,0.0002786346,0.002289057,0.9800121,0.004944052,0.00008787819,0.005904068],"study_design_scores_gemma":[0.00001558104,0.0002609347,0.03086764,0.000009898983,0.0000124541,0.0005373832,0.0001812194,0.02717871,0.9377934,0.00161227,0.001505999,0.00002460282],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969382,0.0001316458,0.001665458,0.00002016,0.000003416257,0.000003221825,0.00004801492,0.00001708604,0.001172759],"genre_scores_gemma":[0.999215,0.00006662201,0.0003613142,0.000003558964,0.00000111846,0.0000027654,0.00005723743,0.000003789346,0.0002886326],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001200778,"threshold_uncertainty_score":0.004016936,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005130766715462406,"score_gpt":0.2243508318121452,"score_spread":0.2192200650966828,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}