{"id":"W2801739651","doi":"10.1002/chem.201802138","title":"Reductive Coupling and Loss of N<sub>2</sub> from Magnesium Diazomethane Derivatives","year":2018,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Diazomethane; Chemistry; Magnesium; Hydrazine (antidepressant); Medicinal chemistry; Silylation; Organic chemistry; Catalysis; Chromatography","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001255656,0.0003559144,0.000118389,0.00009539427,0.0001355996,0.0001105357,0.0003222712,0.0002075763,0.001170288],"category_scores_gemma":[0.0001679078,0.00009249749,0.0001165678,0.00009082768,0.0001847805,0.0001788533,0.0001959222,0.0002853522,0.0002804039],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003206863,"about_ca_system_score_gemma":0.0001927465,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001022998,"about_ca_topic_score_gemma":0.002157636,"domain_scores_codex":[0.9999033,0.000014532,0.000004564113,0.00001624557,0.00002446776,0.00003689258],"domain_scores_gemma":[0.9999574,0.000005956942,0.00001497919,0.000006818586,0.00000643894,0.000008380287],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007783317,0.000007921619,0.00006013931,0.00003769122,0.000005544111,0.00009605461,0.000023349,0.00008924486,0.9983625,0.0001899387,0.00008110052,0.00096859],"study_design_scores_gemma":[0.000008106451,0.00008091579,0.0004462966,0.00000211031,0.000003488543,0.00008496359,0.000008312045,0.000165071,0.997136,0.00004382557,0.002018097,0.000002861803],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9828823,0.0007121963,0.005632611,0.0001623936,0.00005258486,0.00004834075,0.0002071029,0.0001174607,0.01018511],"genre_scores_gemma":[0.9951531,0.000292386,0.00203613,0.0000597896,0.000007384857,0.00001616239,0.0001420862,0.00001987938,0.002273199],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001170288,"threshold_uncertainty_score":0.003914952,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01098894309136982,"score_gpt":0.2165643111163256,"score_spread":0.2055753680249558,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}