{"id":"W2808113437","doi":"10.1039/c8dt01804a","title":"Mechanisms of the H<sub>2</sub>- and transfer hydrogenation of polar bonds catalyzed by iron group hydrides","year":2018,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":39,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Toronto Public Health","funders":"Natural Sciences and Engineering Research Council of Canada; China Scholarship Council; Killam Trusts; University of Toronto; Deutsche Forschungsgemeinschaft; Canada Council for the Arts; Compute Canada; Canada Foundation for Innovation; Ontario Research Foundation","keywords":"Polar; Catalysis; Group (periodic table); Chemistry; Transfer (computing); Organic chemistry; Physics; Computer science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002432326,0.0005941709,0.0003718026,0.0002521574,0.0003368343,0.0003477212,0.0006472909,0.0006491832,0.002766404],"category_scores_gemma":[0.0001386335,0.000209361,0.0003293027,0.00008742576,0.0007166266,0.000923639,0.0004629927,0.0006070111,0.0007007178],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005063002,"about_ca_system_score_gemma":0.000166699,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002933874,"about_ca_topic_score_gemma":0.0003857536,"domain_scores_codex":[0.9999169,0.00001388984,0.000003534706,0.00001018941,0.00002451493,0.00003088642],"domain_scores_gemma":[0.9999664,0.00001531344,0.000008111216,0.000002937128,0.000003103198,0.000004122318],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003922074,0.0002332298,0.001382651,0.003412733,0.0001520563,0.003752595,0.00082518,0.01575049,0.558678,0.3106142,0.006258489,0.09854812],"study_design_scores_gemma":[0.0001276323,0.001536505,0.002568797,0.0002154848,0.00007824948,0.00345542,0.0006074252,0.01994105,0.7850034,0.08845697,0.09790733,0.0001017463],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6521514,0.1351619,0.08487085,0.006638036,0.001593339,0.000470479,0.0003346469,0.0007568035,0.1180225],"genre_scores_gemma":[0.929023,0.05310154,0.005349113,0.0005048738,0.0004387356,0.0001388389,0.0001142328,0.00003244218,0.01129725],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002766404,"threshold_uncertainty_score":0.009254515,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005846362207552224,"score_gpt":0.2017384523282819,"score_spread":0.1958920901207297,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}