{"id":"W2808339198","doi":"10.1002/cctc.201800713","title":"Catalyst Pendent‐Base Effects on Cyclization of Alkynyl Amines","year":2018,"lang":"en","type":"article","venue":"ChemCatChem","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; Western University; University of Ottawa","keywords":"Amine gas treating; Chemistry; Catalysis; Aniline; Ligand (biochemistry); Phosphine; Medicinal chemistry; Polymer chemistry; Coordination sphere; Base (topology); Tertiary amine; Organic chemistry; Metal","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00008269025,0.0002109591,0.0003269259,0.00007293852,0.00007561035,0.00002149132,0.0003140323,0.0001055329,0.006820928],"category_scores_gemma":[0.0001919483,0.0001951387,0.0001574568,0.0002912749,0.0001241451,0.00006578601,0.00008910205,0.00007867494,0.0002544798],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005698928,"about_ca_system_score_gemma":0.00002172619,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004088339,"about_ca_topic_score_gemma":0.00001660351,"domain_scores_codex":[0.9988034,0.000009574443,0.0002943841,0.0003751231,0.0002925151,0.0002249969],"domain_scores_gemma":[0.9987369,0.000148816,0.0001832989,0.0007201325,0.0001139691,0.0000968458],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002645488,0.0001811538,0.0008827121,0.0002779759,0.00009527482,0.000003057561,0.0003137833,2.746217e-7,0.9752775,0.0001273528,0.0005669105,0.02224755],"study_design_scores_gemma":[0.0003188101,0.00002968382,0.0008260678,0.00007101236,0.0001045433,0.00000308237,0.0001425727,0.00004168176,0.9935786,0.0001199353,0.004564757,0.000199221],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9563103,0.0001298469,0.00004648358,0.0001374189,0.00007900472,0.00005057082,0.00001977462,0.00008046628,0.04314611],"genre_scores_gemma":[0.9938493,0.00001290586,0.000123319,0.00006583553,0.000498205,0.00002013229,0.0001379278,0.00003681999,0.005255505],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03789061,"threshold_uncertainty_score":0.994087,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01239111195953727,"score_gpt":0.2321506743965899,"score_spread":0.2197595624370527,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}