{"id":"W2808446465","doi":"10.1021/acscatal.8b01153","title":"Revised Mechanisms for Aldehyde Disproportionation and the Related Reactions of the Shvo Catalyst","year":2018,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Light Source (Canada); Wilfrid Laurier University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation","keywords":"Disproportionation; Catalysis; Chemistry; Hydride; Alkoxide; Aldehyde; Dimer; Ruthenium; Photochemistry; Metal; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005813049,0.0007143119,0.0006330591,0.000690175,0.0003849589,0.001036531,0.002521976,0.001302784,0.004055345],"category_scores_gemma":[0.0007595772,0.0005151579,0.0007523079,0.0001884958,0.001045711,0.002696573,0.0009825249,0.001465096,0.001193936],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001194403,"about_ca_system_score_gemma":0.0003843326,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004850837,"about_ca_topic_score_gemma":0.0004416508,"domain_scores_codex":[0.9996915,0.00003604693,0.00002575871,0.00008035197,0.00009445824,0.00007189918],"domain_scores_gemma":[0.9998846,0.00003080647,0.00001720069,0.00002963671,0.00002362279,0.0000142015],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004167638,0.0001574061,0.001203086,0.002192111,0.00014682,0.001596289,0.0005980308,0.02097213,0.2349256,0.690751,0.002194384,0.04484637],"study_design_scores_gemma":[0.0001996902,0.0005489685,0.0019815,0.0002419244,0.0001376777,0.0029652,0.0006746915,0.1250826,0.4932398,0.2613651,0.1133631,0.0001997315],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5617338,0.08226968,0.2790328,0.007013296,0.002814514,0.0006190566,0.0007090771,0.00110561,0.0647022],"genre_scores_gemma":[0.9566211,0.01463519,0.01311469,0.0004355523,0.0001870995,0.0001980804,0.0003011802,0.00007005104,0.014437],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004055345,"threshold_uncertainty_score":0.01356649,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006832426762297523,"score_gpt":0.2275567163791052,"score_spread":0.2207242896168077,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}