{"id":"W2808978981","doi":"10.1002/anie.201804277","title":"Diastereocontrolled Monoprotodeboronation of β‐Sulfinimido <i>gem</i>‐Bis(boronates): A General and Stereoselective Route to α,β‐Disubstituted β‐Aminoalkylboronates","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":60,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Stereocenter; Stereoselectivity; Chemistry; Geminal; Alkyl; Enantiomer; Aryl; Stereochemistry; Medicinal chemistry; Organic chemistry; Enantioselective synthesis; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001848721,0.0004715518,0.0001820749,0.0002026004,0.0001301751,0.0002146785,0.0002772318,0.0002072867,0.001500129],"category_scores_gemma":[0.0001112494,0.0002446397,0.0001665876,0.000155643,0.0001946653,0.0003436281,0.0003003966,0.000389936,0.0006631836],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002645835,"about_ca_system_score_gemma":0.0003377306,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005417466,"about_ca_topic_score_gemma":0.001168664,"domain_scores_codex":[0.9998921,0.0000190673,0.000008864005,0.00002048971,0.00001755753,0.00004202199],"domain_scores_gemma":[0.9999588,0.00000467053,0.00001361163,0.00000446942,0.000006064266,0.00001241822],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001247655,0.00001896624,0.00006596625,0.00009959991,0.000006642035,0.00007747733,0.00004412122,0.0001629647,0.9940691,0.001167791,0.0001468315,0.004015831],"study_design_scores_gemma":[0.00001491168,0.000137856,0.0002174412,0.000005269311,0.000005435903,0.0001066141,0.00001132228,0.0002652641,0.9961046,0.00008751268,0.003036842,0.000006827221],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9527307,0.003158337,0.0200331,0.0002336311,0.0001204038,0.0001141968,0.0005212073,0.000436289,0.0226521],"genre_scores_gemma":[0.9874204,0.001926317,0.006370642,0.00007117318,0.00001250069,0.00003340213,0.0002900236,0.00005832177,0.003817263],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001500129,"threshold_uncertainty_score":0.005018413,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009688061573126261,"score_gpt":0.2510974562185078,"score_spread":0.2414093946453815,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}