{"id":"W2809128759","doi":"10.1002/anie.201803747","title":"Vinyl Sulfonate Esters: Efficient Chain Transfer Agents for the 3D Printing of Tough Photopolymers without Retardation","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Photopolymerization techniques and applications","field":"Chemistry","cited_by":63,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Christian Doppler Forschungsgesellschaft","keywords":"Photopolymer; Materials science; Polymerization; Methacrylate; Chain transfer; Radical polymerization; Polymer chemistry; Gel point; Transfer printing; Chemical engineering; Polymer; Composite material","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001653191,0.0001406041,0.0001271133,0.00005533425,0.0001595169,0.00003783212,0.0002974548,0.00009113334,0.0009068637],"category_scores_gemma":[0.00007666255,0.0001209224,0.0001122089,0.0001158864,0.0001646546,0.0001160153,0.00003684119,0.00008971363,0.000005072182],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008250098,"about_ca_system_score_gemma":0.00003411834,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006444225,"about_ca_topic_score_gemma":0.000007303727,"domain_scores_codex":[0.9988897,0.000006139714,0.0003645654,0.0002639721,0.0003161508,0.000159504],"domain_scores_gemma":[0.9991562,0.000098059,0.0001767815,0.0002357631,0.0002945858,0.00003859331],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008937358,0.0001079281,0.0001816914,0.00004816279,0.00008559558,1.779621e-7,0.0004969297,0.00004781734,0.9935957,0.001288757,0.001471479,0.002586443],"study_design_scores_gemma":[0.0004862699,0.00001963739,0.00008885966,0.00008380669,0.00004027672,0.000003198845,0.0001519185,0.01035292,0.9682884,0.0001760702,0.02018353,0.000125076],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.4835241,0.00007088916,0.4866977,0.001916132,0.001032686,0.0007629478,0.000788927,0.0003171645,0.02488938],"genre_scores_gemma":[0.99637,0.0000481581,0.000599479,0.0002352656,0.00103979,0.0003427096,0.0006724398,0.00002466421,0.0006675366],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.5128458,"threshold_uncertainty_score":0.9929522,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02082099819522227,"score_gpt":0.2851721497228887,"score_spread":0.2643511515276665,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}