{"id":"W2809576596","doi":"10.1002/chem.201802732","title":"Cover Feature: Reductive Coupling and Loss of N<sub>2</sub> from Magnesium Diazomethane Derivatives (Chem. Eur. J. 34/2018)","year":2018,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Chemical Reactions and Isotopes","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Diazomethane; Steric effects; Magnesium; Chemistry; Coupling (piping); Cover (algebra); Feature (linguistics); Combinatorial chemistry; Computational chemistry; Medicinal chemistry; Stereochemistry; Organic chemistry; Materials science; Metallurgy; Philosophy; Engineering","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005784338,0.0002690605,0.0003125871,0.00003900795,0.0002803318,0.00005098782,0.0002807575,0.0001590104,0.001054373],"category_scores_gemma":[0.0003628217,0.0002461868,0.0001135114,0.0001833008,0.0008937201,0.0001627271,0.000162025,0.001235285,0.00007314765],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006780514,"about_ca_system_score_gemma":0.00007061561,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000158722,"about_ca_topic_score_gemma":1.561523e-7,"domain_scores_codex":[0.9985749,0.0001583779,0.0003931304,0.0003449026,0.0001697295,0.0003589904],"domain_scores_gemma":[0.9985366,0.0002718121,0.0003723566,0.0001982399,0.000247873,0.0003730871],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004080459,0.0001535362,0.001153058,0.00004935243,0.0001645279,0.000101774,0.0004504456,0.000007580314,0.9873438,0.000003101626,0.007076215,0.003088497],"study_design_scores_gemma":[0.001453554,0.00008715256,0.002541717,0.00005245834,0.0001591062,0.0003507995,0.0002565723,0.0003654736,0.9616879,0.0001032933,0.03268435,0.0002575986],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9909251,0.001200501,0.0002001396,0.0004584264,0.0004554032,0.00008218072,0.00008696641,0.0000322199,0.006559079],"genre_scores_gemma":[0.9960859,0.0007565436,0.0003832359,0.0002156344,0.00185975,0.000002436835,0.00002485508,0.00004412155,0.0006275027],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02565594,"threshold_uncertainty_score":0.999999,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05040036409399955,"score_gpt":0.3411205857864174,"score_spread":0.2907202216924178,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}